Mathematical formulation of quantum mechanics

The mathematical formulations of quantum mechanics are those mathematical formalisms that permit a rigorous description of quantum mechanics. Such are distinguished from mathematical formalisms for theories developed prior to the early 1900s by the use of abstract mathematical structures, such as infinite-dimensional Hilbert spaces and operators on these spaces. Many of these structures are drawn from functional analysis, a research area within pure mathematics that was influenced in part by the needs of quantum mechanics. In brief, values of physical observables such as energy and momentum were no longer considered as values of functions on phase space, but as eigenvalues; more precisely: as spectral values (point spectrum plus absolute continuous plus singular continuous spectrum) of linear operators in Hilbert space.

These formulations of quantum mechanics continue to be used today. At the heart of the description are ideas of quantum state and quantum observable which are radically different from those used in previous models of physical reality. While the mathematics permits calculation of many quantities that can be measured experimentally, there is a definite theoretical limit to values that can be simultaneously measured. This limitation was first elucidated by Heisenberg through a thought experiment, and is represented mathematically in the new formalism by the non-commutativity of operators representing quantum observables.

Quantum mechanics

Quantum mechanics (QM; also known as quantum physics or quantum theory) including quantum field theory, is a fundamental branch of physics concerned with processes involving, for example, atoms and photons. In such processes, said to be quantized, the action has been observed to be only in integer multiples of the Planck constant, a physical quantity that is exceedingly, indeed perhaps ultimately, small. This is utterly inexplicable in classical physics.

Quantum mechanics gradually arose from Max Planck's solution in 1900 to the black-body radiation problem (reported 1859) and Albert Einstein's 1905 paper which offered a quantum-based theory to explain the photoelectric effect (reported 1887). Early quantum theory was profoundly reconceived in the mid-1920s.

The reconceived theory is formulated in various specially developed mathematical formalisms. In one of them, a mathematical function, the wave function, provides information about the probability amplitude of position, momentum, and other physical properties of a particle.

Introduction to quantum mechanics

Quantum mechanics is the science of the very small: the body of scientific principles that explains the behaviour of matter and its interactions with energy on the scale of atoms and subatomic particles.

Classical physics explains matter and energy on a scale familiar to human experience, including the behaviour of astronomical bodies. It remains the key to measurement for much of modern science and technology. However, towards the end of the 19th century, scientists discovered phenomena in both the large (macro) and the small (micro) worlds that classical physics could not explain. As Thomas Kuhn explains in his analysis of the philosophy of science, The Structure of Scientific Revolutions, coming to terms with these limitations led to two major revolutions in physics which created a shift in the original scientific paradigm: the theory of relativity and the development of quantum mechanics. This article describes how physicists discovered the limitations of classical physics and developed the main concepts of the quantum theory that replaced it in the early decades of the 20th century. These concepts are described in roughly the order in which they were first discovered. For a more complete history of the subject, see History of quantum mechanics.