History of quantum mechanics

The history of quantum mechanics is a fundamental part of the history of modern physics. Quantum mechanics' history, as it interlaces with the history of quantum chemistry, began essentially with a number of different scientific discoveries: the 1838 discovery of cathode rays by Michael Faraday; the 1859–60 winter statement of the black-body radiation problem by Gustav Kirchhoff; the 1877 suggestion by Ludwig Boltzmann that the energy states of a physical system could be discrete; the discovery of the photoelectric effect by Heinrich Hertz in 1887; and the 1900 quantum hypothesis by Max Planck that any energy-radiating atomic system can theoretically be divided into a number of discrete "energy elements" ε (epsilon) such that each of these energy elements is proportional to the frequency ν with which each of them individually radiate energy, as defined by the following formula:

where h is a numerical value called Planck's constant.

Then, Albert Einstein in 1905, in order to explain the photoelectric effect previously reported by Heinrich Hertz in 1887, postulated consistently with Max Planck's quantum hypothesis that light itself is made of individual quantum particles, which in 1926 came to be called photons by Gilbert N. Lewis. The photoelectric effect was observed upon shining light of particular wavelengths on certain materials, such as metals, which caused electrons to be ejected from those materials only if the light quantum energy was greater than the work function of the metal's surface.

Quantum mechanics

Quantum mechanics (QM; also known as quantum physics or quantum theory) including quantum field theory, is a fundamental branch of physics concerned with processes involving, for example, atoms and photons. In such processes, said to be quantized, the action has been observed to be only in integer multiples of the Planck constant, a physical quantity that is exceedingly, indeed perhaps ultimately, small. This is utterly inexplicable in classical physics.

Quantum mechanics gradually arose from Max Planck's solution in 1900 to the black-body radiation problem (reported 1859) and Albert Einstein's 1905 paper which offered a quantum-based theory to explain the photoelectric effect (reported 1887). Early quantum theory was profoundly reconceived in the mid-1920s.

The reconceived theory is formulated in various specially developed mathematical formalisms. In one of them, a mathematical function, the wave function, provides information about the probability amplitude of position, momentum, and other physical properties of a particle.

Mathematical formulation of quantum mechanics

The mathematical formulations of quantum mechanics are those mathematical formalisms that permit a rigorous description of quantum mechanics. Such are distinguished from mathematical formalisms for theories developed prior to the early 1900s by the use of abstract mathematical structures, such as infinite-dimensional Hilbert spaces and operators on these spaces. Many of these structures are drawn from functional analysis, a research area within pure mathematics that was influenced in part by the needs of quantum mechanics. In brief, values of physical observables such as energy and momentum were no longer considered as values of functions on phase space, but as eigenvalues; more precisely: as spectral values (point spectrum plus absolute continuous plus singular continuous spectrum) of linear operators in Hilbert space.

These formulations of quantum mechanics continue to be used today. At the heart of the description are ideas of quantum state and quantum observable which are radically different from those used in previous models of physical reality. While the mathematics permits calculation of many quantities that can be measured experimentally, there is a definite theoretical limit to values that can be simultaneously measured. This limitation was first elucidated by Heisenberg through a thought experiment, and is represented mathematically in the new formalism by the non-commutativity of operators representing quantum observables.

Introduction to quantum mechanics

Quantum mechanics is the science of the very small: the body of scientific principles that explains the behaviour of matter and its interactions with energy on the scale of atoms and subatomic particles.

Classical physics explains matter and energy on a scale familiar to human experience, including the behaviour of astronomical bodies. It remains the key to measurement for much of modern science and technology. However, towards the end of the 19th century, scientists discovered phenomena in both the large (macro) and the small (micro) worlds that classical physics could not explain. As Thomas Kuhn explains in his analysis of the philosophy of science, The Structure of Scientific Revolutions, coming to terms with these limitations led to two major revolutions in physics which created a shift in the original scientific paradigm: the theory of relativity and the development of quantum mechanics. This article describes how physicists discovered the limitations of classical physics and developed the main concepts of the quantum theory that replaced it in the early decades of the 20th century. These concepts are described in roughly the order in which they were first discovered. For a more complete history of the subject, see History of quantum mechanics.