The GSh-18 (Cyrillic: ГШ-18) is a 9 mm semi-automatic pistol developed by the KBP Instrument Design Bureau in Tula during the 1990s. The pistol's name is derived from its designers — Gryazev and Shipunov, and the number 18 denotes the magazine capacity.
The GSh-18 is a rotating-barrel, short recoil, locked-breech pistol with 10 locking lugs spaced equally around the barrel, the large locking surface area resulting in a strong lockup, making it suitable for high-velocity ammunition loads. The GSh-18 may be employed using standard 9x19mm Parabellum rounds, but was designed for the high velocity, Russian armour-piercing 7N31 9x19mm round. The pistol incorporates a pre-set striker.. The slide and working parts are steel, and the weapon has a polymer frame. Two different designs of grip have been observed. The magazine capacity is 18 rounds, and an additional round may be carried in the chamber. Unusually for a pistol, the magazines are of the two-position feed type, meaning the rounds feed into the chamber from alternate left and right positions in the magazine similar to most rifles, instead of the single-position feed type used by the Browning Hi-Power and derivatives, where the staggered column of rounds is compressed into a single column as they rise to the top of the magazine. Disassembly is slightly more complex, with more dismountable parts, than a typical Browning derivative, such as the SIG Sauer P226, Glock 17 or CZ-75. The magazine release is reversible for left-handed shooters and the ejector doubles as a loaded chamber indicator.
Glutathione (GSH) is an important antioxidant in plants, animals, fungi, and some bacteria and archaea, preventing damage to important cellular components caused by reactive oxygen species such as free radicals, peroxides, lipid peroxides and heavy metals. It is a tripeptide with a gamma peptide linkage between the carboxyl group of the glutamate side-chain and the amine group of cysteine (which is attached by normal peptide linkage to a glycine).
Thiol groups are reducing agents, existing at a concentration around 5 mM in animal cells. Glutathione reduces disulfide bonds formed within cytoplasmic proteins to cysteines by serving as an electron donor. In the process, glutathione is converted to its oxidized form, glutathione disulfide (GSSG), also called L-(–)-glutathione.
Once oxidized, glutathione can be reduced back by glutathione reductase, using NADPH as an electron donor. The ratio of reduced glutathione to oxidized glutathione within cells is often used as a measure of cellular toxicity.
The Gryazev-Shipunov GSh-6-30 (Russian: Грязев-Шипунов ГШ-6-30) is a Russian 30 mm Gatling-style aircraft-mounted and naval autocannon used by Soviet and later CIS military aircraft. The GSh-6-30 fires a 30×165mm, 390 g (13¾ oz) projectile.
The GSh-6-30, designed in the early 1970s and entering service in 1975, has a six barrel design that is similar to the Gryazev-Shipunov GSh-6-23. It was based on the naval AO-18 used in the AK-630 system. Unlike most modern American rotary cannons, it is gas-operated rather than hydraulically driven, allowing it to "spin up" to maximum rate of fire more quickly, allowing more rounds to be placed on target in a short-duration burst. This makes the weapon advantageous in dogfights, where pilots often have a very small window for engaging the enemy. Ignition is electrical, as with the smaller GSh-6-23.
On the Mikoyan MiG-27 the GSh-6-30 had to be mounted obliquely to absorb recoil. The gun was noted for its high (often uncomfortable) vibration and extreme noise. The airframe vibration led to fatigue cracks in fuel tanks, numerous radio and avionics failures, the necessity of using runways with floodlights for night flights (as the landing lights would often be destroyed), tearing or jamming of the forward landing gear doors (leading to at least three crash landings), cracking of the reflector gunsight, an accidental jettisoning of the cockpit canopy and at least one case of the instrument panel falling off in flight. The weapons also dealt extensive collateral damage, as the sheer numbers of fragments from detonating shells was sufficient to damage aircraft flying within a 200 meter radius from the impact center, including the aircraft firing.
The Gryazev-Shipunov GSh-30-1 (the actual Russian designation is GSh-301; also known by the GRAU index designation 9A-4071K) is a 30 mm autocannon designed for use on Soviet and later Russian military aircraft, entering service in the early 1980s. Its current manufacturer is the Russian company Izhmash JSC.
The GSh-301 is a single-barreled, recoil operated autocannon weighing 46 kg (101 lb). Unlike many postwar cannons, it uses a short recoil action instead of a revolver cannon or Gatling gun mechanism. This results in a reduced rate of fire, but lower weight and bulk.
The GSh-301 has a rate of fire of 1,800 rounds per minute, customarily limited to 1,500 rounds per minute to reduce barrel wear. Despite that, its barrel life is quite short: 2,000 rounds. When firing a continuous burst of 100–150 rounds, the barrel is put under so much stress that it has to be replaced. The gun uses an evaporation cooling system to prevent the detonation of a high explosive round inside a heated barrel. This cooling system consists of a cylindrical water tank around the rear end of the barrel. The GSh-301 is equipped with a unique pyrotechnic mechanism to clear misfires: a small pyrotechnic cartridge is located to the left of the 30mm cartridge chamber. This pyrotechnic cartridge fires a small steel bolt through the side wall of the 30mm cartridge. The hot propellant gases following the bolt into the dud 30mm round ignite the powder charge of that round and firing continues.