Fermi surface

In condensed matter physics, the Fermi surface is an abstract boundary in reciprocal space useful for predicting the thermal, electrical, magnetic, and optical properties of metals, semimetals, and doped semiconductors. The shape of the Fermi surface is derived from the periodicity and symmetry of the crystalline lattice and from the occupation of electronic energy bands. The existence of a Fermi surface is a direct consequence of the Pauli exclusion principle, which allows a maximum of one electron per quantum state.

Theory

Consider a spinless ideal Fermi gas of N particles. According to Fermi–Dirac statistics, the mean occupation number of a state with energy \epsilon_i is given by

\langle n_i\rangle =\frac{1}{e^{(\epsilon_i-\mu)/k_BT}+1},

where,

  • \left\langle n_i\right\rangle is the mean occupation number of the i^{th} state
  • \epsilon_i is the kinetic energy of the i^{th} state
  • \mu is the internal chemical potential (at zero temperature, this is the maximum kinetic energy the particle can have, i.e. Fermi energy \epsilon_F)
  • T is the absolute temperature
  • k_B is the Boltzmann constant

  • Suppose we consider the limit T\to 0. Then we have,

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