Ester pyrolysis

Ester pyrolysis in organic chemistry is a vacuum pyrolysis reaction converting esters containing a β-hydrogen atom into the corresponding carboxylic acid and the alkene. The reaction is an Ei elimination.

Examples are the synthesis of acrylic acid from ethyl acrylate at 590 °C, the synthesis of 1,4-pentadiene from 1,5-pentanediol diacetate at 575 °C or the construction of a cyclobutene framework at 700 °C

References

ester pyrolysis is a syn elimination

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