Depletion gilding
Depletion gilding is a method for producing a layer of nearly pure gold on an object made of gold alloy by removing the other metals from its surface. It is sometimes referred to as a "surface enrichment" process.
Process
Most gilding methods are additive, that is, they deposit gold that was not there before onto the surface of an object. By contrast, depletion gilding is a subtractive process whereby material is removed to increase the purity of gold that is already present on an object's surface.
Essentially, depletion gilding produces a high-purity gold surface by removing everything that is not gold. More specifically, other metals are etched away from the surface of an object composed of a gold alloy by the use of acids or salts, often in combination with heat. Of course, since no gold is actually added, only an object made of an alloy that already contains at least some gold can be depletion gilded.
Depletion gilding relies on the fact that gold is highly resistant to oxidation or corrosion by most common chemicals, whereas many other metals are not. Depletion gilding is most often used to treat alloys of gold with copper and/or silver. Unlike gold, both copper and silver readily react with a variety of chemicals. For example, nitric acid is effective as an etching agent for both copper and silver. Under the proper circumstances, even ordinary table salt (sodium chloride) will react with either metal.