Chirality

Chirality /kaɪˈrælɪtiː/ is a property of asymmetry important in several branches of science. The word chirality is derived from the Greek, χειρ (kheir), "hand", a familiar chiral object.

An object or a system is chiral if it is distinguishable from its mirror image; that is, it cannot be superposed onto it. Conversely, a mirror image of an achiral object, such as a sphere, cannot be distinguished from the object. A chiral object and its mirror image are called enantiomorphs (Greek opposite forms) or, when referring to molecules, enantiomers. A non-chiral object is called achiral (sometimes also amphichiral) and can be superposed on its mirror image. If the object is non-chiral and is imagined as being colored blue and its mirror image is imagined as colored yellow, then by a series of rotations and translations the two can be superposed producing green with none of the original colors remaining.

The term was first used by Lord Kelvin in 1893 in the second Robert Boyle Lecture at the Oxford University Junior Scientific Club which was published in 1894:

Chirality (electromagnetism)

The term chiral /ˈkaɪərəl/ describes an object, especially a molecule, which has or produces a non-superimposable mirror image of itself. In chemistry, such a molecule is called an enantiomer or is said to exhibit chirality or enantiomerism. The term "chiral" comes from the Greek word for the human hand, which itself exhibits such non-superimposeability of the left hand precisely over the right. Due to the opposition of the fingers and thumbs, no matter how the two hands are oriented, it is impossible for both hands to exactly coincide. Helices, chiral characteristics (properties), chiral media, order, and symmetry all relate to the concept of left- and right-handedness.

Wave propagation as handedness

Electromagnetic wave propagation as handedness is wave polarization and described in terms of helicity (occurs as a helix). Polarization of an electromagnetic wave is the property that describes the orientation, i.e., the time-varying, direction (vector), and amplitude of the electric field vector. For a depiction, see the image to the left.

Chirality (physics)

A chiral phenomenon is one that is not identical to its mirror image (see the article on mathematical chirality). The spin of a particle may be used to define a handedness, or helicity, for that particle, which, in the case of a massless particle, is the same as chirality. A symmetry transformation between the two is called parity. Invariance under parity by a Dirac fermion is called chiral symmetry.

An experiment on the weak decay of cobalt-60 nuclei carried out by Chien-Shiung Wu and collaborators in 1957 demonstrated that parity is not a symmetry of the universe.

Chirality and helicity

The helicity of a particle is right-handed if the direction of its spin is the same as the direction of its motion. It is left-handed if the directions of spin and motion are opposite. By convention for rotation, a standard clock, with its spin vector defined by the rotation of its hands, tossed with its face directed forwards, has left-handed helicity. Mathematically, helicity is the sign of the projection of the spin vector onto the momentum vector: left is negative, right is positive.