Carminic acid[1]
Identifiers
CAS number 1260-17-9 YesY
ChemSpider 14068 YesY
UNII CID8Z8N95N YesY
KEGG C11254 YesY
ChEMBL CHEMBL263094
Jmol-3D images Image 1
Properties
Molecular formula C22H20O13
Molar mass 492.38 g/mol
Density  ? g/cm3
Melting point

120 °C (decomp.)

 YesY (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Carminic acid (C22H20O13) is a red glucosidal hydroxyanthrapurin that occurs naturally in some scale insects, such as the cochineal and the Polish cochineal. The insects produce the acid as a deterrent to predators. Carminic acid is the colouring agent in carmine. Synonyms are C.I. 75470 and C.I. Natural Red 4.

The chemical structure of carminic acid consists of a core anthraquinone structure linked to a glucose sugar unit. Carminic acid was first synthesized by organic chemists in 1991.[2]

References [link]

  1. ^ Merck Index, 11th Edition, 1850.
  2. ^ Allevi, P. et al. (1991). "The 1st Total Synthesis of Carminic Acid". Journal of the Chemical Society-Chemical Communications 18: 1319–1320. 

https://wn.com/Carminic_acid

Crimson

Crimson is a strong, red color, inclining to purple. It originally meant the color of the kermes dye produced from a scale insect, Kermes vermilio, but the name is now sometimes also used as a generic term for slightly bluish-red colors that are between red and rose.

History

Crimson (NR4) is produced using the dried bodies of the kermes insect, which were gathered commercially in Mediterranean countries, where they live on the kermes oak, and sold throughout Europe. Kermes dyes have been found in burial wrappings in Anglo-Scandinavian York. They fell out of use with the introduction of cochineal, because although the dyes were comparable in quality and color intensity it needed ten to twelve times as much kermes to produce the same effect as cochineal.

Carmine is the name given to the dye made from the dried bodies of the female cochineal, although the name crimson is sometimes applied to these dyes too. Cochineal appears to have been brought to Europe during the conquest of Mexico by the Spaniard Hernán Cortés, and the name 'carmine' is derived from the French carmin. It was first described by Mathioli in 1549. The pigment is also called cochineal after the insect from which it is made.

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