Calcium sulfate

Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO4 and related hydrates. In the form of γ-anhydrite (the anhydrous form), it is used as a desiccant. One particular hydrate is better known as plaster of Paris, and another occurs naturally as the mineral gypsum. It has many uses in industry. All forms are white solids that are poorly soluble in water.

Structures

The compound exists in three levels of hydration:

  • anhydrous state (mineral name: "anhydrite") with the formula CaSO4.
  • dihydrate (mineral name: "gypsum") with the formula CaSO4(H2O)2.
  • hemihydrate with the formula CaSO4(H2O)0.5. Specific hemihydrates are sometimes distinguished: alpha-hemihydrate and beta-hemihydrate.
  • Uses

    The main use of calcium sulfate is to produce Plaster of Paris and stucco. These applications exploit the fact that calcium sulfate forms a moldable paste upon hydration and hardens as a hemihydrate. It is also convenient that calcium sulfate is very poorly soluble in water, so structures do not dissolve.

    Calcium sulfate (data page)

    This page provides supplementary chemical data on calcium sulfate.

    Material Safety Data Sheet

    The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the material safety data sheet for this chemical from a reliable source and follow its directions.

  • Calcium Sulfate Dihydrate: Excaliber Minerals LLC
  • Calcium Sulfate Anhydrous: ScienceLab.com, Inc.
  • Structure and properties

    Thermodynamic properties

    Spectral data

    References

    Except where noted otherwise, data relate to standard ambient temperature and pressure.

    Disclaimer applies.

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