Butyl

In organic chemistry, butyl is a four-carbon alkyl radical or substituent group with general chemical formula -C4H9, derived from either of the two isomers of butane.

The isomer n-butane can connect either at one of the two terminal carbon atoms or at one of the two internal carbon atoms, giving rise to two "-butyl" groups:

  • Normal butyl or n-Butyl: CH3–CH2–CH2–CH2– (fully systematic name: butyl)
  • Secondary butyl or sec-Butyl: CH3–CH2–CH(CH3)– (fully systematic name: 1-methylpropyl)
  • The second, branched isomer of butane, isobutane, can connect either at one of the three terminal carbons or at the central carbon, giving rise to another two groups:

  • Isobutyl: (CH3)2CH–CH2– (fully systematic name: 2-methylpropyl)
  • Tertiary butyl, tert-Butyl or t-butyl: (CH3)3C– (fully systematic name: 1,1-dimethylethyl)
  • Nomenclature

    According to IUPAC nomenclature, "isobutyl", "sec-butyl", and "tert-butyl" are all retained names.

    Butyl is the largest substituent for which trivial names are commonly used for all isomers.

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