Picoline
Picoline refers to three different methylpyridine isomers, all with the chemical formula C6H7N and a molar mass of 93.13 g mol−1. All three are colourless liquids at room temperature and pressure, with a characteristic smell similar to pyridine. They are miscible with water and most organic solvents. Data for the three compounds are summarized in the table. Picolines are derivatives of picoline.
The CAS number of an unspecified picoline isomer is [1333-41-1]
Environmental properties
Picolines exhibit greater volatility and are more slowly degraded than their carboxylic acid counterparts. Volatilization is much less extensive in soil than water, owing to sorption of the compounds to soil clays and organic matter. Picoline degradation appears to be mediated primarily by bacteria, with the majority of isolates belonging to the Actinobacteria. 3-Methylpyridine degrades more slowly than the other two isomers, likely due to the impact of resonance in the heterocyclic ring. Like most simple pyridine derivatives, the picolines contain more nitrogen than is needed for growth of microorganisms, and excess nitrogen is generally excreted to the environment as ammonium during the degradation process.
4-Methylpyridine
4-Methylpyridine is the organic compound with the formula CH3C5H4N. It is one of the three isomers of methylpyridine. This pungent liquid is a building block for the synthesis of other heterocyclic compounds. Its conjugate acid, the 4-methylpyridinium ion, has a pKa of 5.98, about 0.7 units above that of pyridine itself.
Production and uses
4-Methylpyridine is both isolated from coal tar and is synthesized industrially. It forms via the reaction of acetaldehyde and ammonia in the presence of an oxide catalyst. The method also affords some 2-methylpyridine. 4-methylpyridine is of little intrinsic value but is a precursor to other commercially significant species, often of medicinal interest. Ammoxidation of 4-methylpyridine gives 4-cyanopyridine, the precursor to a variety of other derivatives such as the antituberculosis drug Isoniazid (isonicotinic hydrazide).
References
Podcasts:
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by Boo Clan
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by Boo Clan
The Juggalette Song
by: Boo Clan(Chorus)
Nothin on this earth can rock me
Like a juggalette
Kissing up and down her neck and
Talking dirty til she gets wet
Ladies in clown makeup and
Milenko thongs listen up
I'm a spit this lyrical message
Until I've had enough
(Chorus)
Nothin on this earth can rock me
Like a juggalette
Kissing up and down her neck and
Talking dirty til she gets wet
Take this for example,
Recently there's been a lady
Gorgeous Juggalette who
I can call my brunette baby
Loves it when I hold her tight and
Stick my hands between her thighs
Tears of ecstacy and passion
Slowly drippin from her eyes
Took her panties off
And rolled my tongue right down
Her f***ing chest
To the best p***y ever tasted,
F*** it was the best
Reached up with my arms
And she grabbed and
Tightly held my hands
Telling me how good it felt
So I continued with my plans
Dug a little deeper with my tongue
Until I hit the knot
Gripped my hands tighter
As my tongue tickled her G spot
Next thing that we did was
To create one being from two
Got her up on top and
F***ed her as the Juggalos do
Never felt the passion from
Another Juggalette before
That was days ago
And I'm still here cravin more
Gotta tell this Juggalette
In some form, in some way
I still got more to say and that
Boo still wants to play
This song goes out to all of you Psychopathic Juggalettes
Listen to me closely so that
I can get this off my chest
(Chorus)
Nothin on this earth can rock me
Like a juggalette
Kissing up and down her neck and
Talking dirty til she gets wet
Juggalettes listen up,
I'm a talk about them
Silly f*ggot pop punks
Them jockey sports hunks
The ones that dress to impress
And always buy from the best
The f**k they got to offer you
Besides a shaved chest?
It's what a juggalo like me can
Offer you just every time
Pourin' Faygo down ya t! ts
As we hand you to the sweet sublime
A juggalo will strip you down and
F**k you in his facepaint
Chew off your panties and
Lick your p***y til you faint
This song goes out to all of you Psychopathic Juggalettes
Listen to me closely so that
I can get this off my chest
(Chorus)
Nothin on this earth can rock me
Like a juggalette
Kissing up and down her neck and
Talking dirty til she gets wet
This song goes out to all of you Psychopathic Juggalettes
Listen to me closely so that
I can get this off my chest
(Chorus)
Nothin on this earth can rock me
Like a juggalette
Kissing up and down her neck and
Talking dirty til she gets wet
This song goes out to all of you Psychopathic Juggalettes
Listen to me closely so that
I can get this off my chest
(Chorus)
Nothin on this earth can rock me
Like a juggalette
Kissing up and down her neck and