Ejercicio 20 3 Expansor
Ejercicio 20 3 Expansor
Ejercicio 20 3 Expansor
-100
600
F
Lpca
Tc =
Pc =
Pd =
Tasa =
nis =
120
2744
80%
Lpca
Lbmol/hr
PM =
-116.66 F
667 Lpca
16.043 Lbm/Lbmol
380
Btu/Lbm
340
Btu/Lbm
T2 =
-200
(vapor sobrecalentado)
Wm ax =
W max =
m(h2 h1 )
2544
-43.1
hp
h2
real
= ( h2 h1 ) is + h1
h2 real =
Wreal =
W real =
348
Btu/Lbm
m(h2 real h1 )
2544
-34.5
hp
14/06/2007
-200
Metodo Analitoco
Ts =
-100
Ps =
600
Lpca
Pd =
120
Lpca
r=
0.200
K@Tprom=
1.3371
)(rreal _ 2 ) K
T d 2 = (T s 2 + 460
Td =
-220
Tprom =
F
460
-160
H is =
1545 Z aver T s
PM ( K 1) K
His =
K 1
r K 1
-34788.77 Lbf.Pie/Lbm
Wm ax =
W max =
m H is
33000
-48.21
HP
Wreal =
W real =
m H is is
33000
-38.57
HP
14/06/2007
2-. Un turbo-expansor trabaja con gas natural de composicion conocida inicialmente a 800 Lpca y 20 F.
El valor P1/P2 es de 2:1. El proceso tiene una eficiencia adiabatica del 82%. Determine:
a) El trabajo real.
b) El trabajo maximo.
c) La temperatura real final
Comp
C1
% yi
80.8
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
12.2
4.2
0.7
1.1
0.3
0.4
0.1
0.2
100
PMC7+ =
122
C7+ =
0.73
Ts =
Ps =
Pd =
Tasa =
Moles =
20
800
400
500
52219
Lbm/lbmol
F
Lpca
Lpca
MMpcnd
Lbmol/hr
PM 0.9371
Tb =
5
1 .4350476 10
Tb C7+ =
725.5
2.3776
1034.9
wC 7 + =
w C7+ =
373.4
Lpca
3 Log sPc
7
14 .7
sTc
1
Tbn
0.4117
yi
0.808
0.122
0.042
0.007
0.011
0.003
0.004
0.001
0.002
1.00
w
0.0108
0.0972
0.1515
0.1852
0.1981
0.2286
0.2510
0.2990
0.4117
Tci
343.3
550.1
665.9
734.4
765.5
829.0
845.7
911.8
1034.9
Pci
667.0
707.8
615.0
527.9
548.8
490.4
488.1
439.5
373.4
Tbn
201.3
332.5
416.3
470.8
491.1
540.1
556.9
615.7
725.5
14/06/2007
Pk
fw (xi)
Ki
sTcC2+
Pk (Hadden)
y = 1
x = 1
Comparar
donde:
x
sTc C 2 + =
PM i Tc i
xi =
2
n
x PM
i
zi
( K i 1) V + 1
y i = K i xi
zi
0.8080
0.1220
0.0420
0.0070
0.0110
0.0030
0.0040
0.0010
0.0020
sTcC2+ =
670.0
210.0
Ki
2.8000
0.5400
0.1900
0.0890
0.0650
0.0315
0.0265
0.0097
0.0015
V=
xi
0.298
0.217
0.183
0.053
0.100
0.038
0.054
0.017
0.040
1.000
Tci2 R2
117882.4
302577
443449.4
539358
586005.6
687174.7
715208.5
831379.2
1070967
0.951
yi
0.834
0.117
0.035
0.005
0.006
0.001
0.001
0.000
0.000
1.000
xiPMi
xiPMiTci
1.957
1.263
0.309
0.639
0.174
0.289
0.072
0.172
4.876
1076.6
841.0
226.7
489.4
144.5
244.1
65.8
178.4
3266.5
R
F
x
sTc
C 2+
PM
Tc i
2
n
PM
En la Fig. 23-2, Cap.23 del GPSA, el valor de la (Tc)C2+ se encuentra entre la (Tc)C3 = 205.92 F
y la (Tc)iC4 = 274.41F. En la Fig. 25-11 del GPSA (graf de Hadden), se construye una curva la
cual estar entre los componentes C3 y CiC4, y con la (Tc)C2+ se corta la curva de unin entre el
C3 y el iC4, luego este punto se une con el punto del componente C1; se traza una curva y con
la T = 20 F se corta la curva y se obtiene una Pk = 1500 lpca.
Pk
Ki
fw (xi)
sTcC2+
Pk (Hadden)
y = 1
x = 1
Comparar
14/06/2007
Fase gaseosa
Temp =
presin =
C7+ =
20.0
800
0.73
Comp
C1
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
yi
0.8340
0.1172
0.0348
0.0047
0.0065
0.0012
0.0014
0.0002
0.0001
sTr =
sPr =
1.247
1.198
F
Lpca
PMi
16.04
30.07
44.10
58.12
58.12
72.15
72.15
86.18
122.00
hi
239.2
146.9
124.5
118.0
124.5
118.0
120.5
107.1
102.0
yiPMihi
3199.9
517.6
191.0
32.1
46.9
10.2
12.5
1.6
0.8
4012.5
(0)
H H P ,T
R sTc
(I )
H H P ,T
R sTc
yiTci
286.4
64.4
23.2
3.4
5.0
1.0
1.2
0.2
0.1
384.8
1.10
0.28
H H P ,T
H H P ,T
+ w
= R sTc
R sTc
R sTc
=
846.73 Btu/Lbmol
Hp , t = Hm H H P ,T
(0 )
H H P ,T
H H P ,T
Hp,t =
3165.8
(I )
yiPci
556.3
82.9
21.4
2.5
3.6
0.6
0.7
0.1
0.0
668.0
yiwi
0.0090
0.0114
0.0053
0.0009
0.0013
0.0003
0.0004
0.0001
0.0000
0.0285
PMiewi
16.217
33.140
51.310
69.949
70.857
90.681
92.735
184.144
Grafico
TciHi0.5/PMi
331.0
221.7
168.5
137.2
146.9
124.8
128.6
85.7
Btu/Lbmol
Fase gaseosa
Temp =
Presin =
20
800
Comp
C1
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
yi
0.8340
0.1172
0.0348
0.0047
0.0065
0.0012
0.0014
0.0002
0.0001
F
Lpca
PMi
16.043
30.070
44.097
58.123
58.123
72.150
72.150
86.177
122.00
si
3.049
1.956
1.545
1.316
1.255
1.185
1.166
1.125
1.099
yiPMisi
40.79
6.89
2.37
0.36
0.47
0.10
0.12
0.02
0.01
51.1
yilnyi
-0.151
-0.251
-0.117
-0.025
-0.033
-0.008
-0.009
-0.001
-0.001
-0.597
yiTci
286.4
64.4
23.2
3.4
5.0
1.0
1.2
0.2
0.1
384.8
yiPci
556.3
82.9
21.4
2.5
3.6
0.6
0.7
0.1
0.0
668.0
xiwi
0.0090
0.0114
0.0053
0.0009
0.0013
0.0003
0.0004
0.0001
0.0000
0.0285
14/06/2007
sTr =
sPr =
S S P ,T
1.247
1.198
S S P ,T
(0)
0.50
Grafico
Tc.ln(PM)/ln(Tbn)
180
322
418
485
502
564
572
(I )
0.24
Sm = Yi Si PMi R Yi Ln (Yi )
Sm =
S S P ,T
S S P ,T
52.32
43.374
38.311
15.521
11.043
9.012
8.257
7.486
6.896
Btu/Lbmol R
S S P ,T ( 0 )
S S P ,T
+ w
= R
R
R
= 8.94 Btu/Lbmol R
Sp,t =
Ln(PM).ln(1/w).S
(I )
+ Ln ( P / 14 .7 )
Btu/Lbmol R
Pk
xi = zi/Ki
fw (xi)
sTcC2+
Pk (Hadden)
zi/Ki = 1
Comparar
donde:
x
sTc C 2 + =
PM i Tc i
2
n
x PM
i
zi
0.8340
0.1172
0.0348
0.0047
0.0065
0.0012
0.0014
0.0002
0.0001
Ki
4.7000
0.8000
0.2300
0.0960
0.0700
0.0280
0.0240
0.0077
0.0009
Tci2 R2
117882
302577
443449
539358
586006
687175
715208
831379
1070967
zi/Ki
0.1775
0.1464
0.1513
0.0487
0.0925
0.0430
0.0599
0.0218
0.0657
0.807
dado que zi/Ki < 1 debemos asumir temperaturas inferiores a la supuesta (20 F)
14/06/2007
zi
0.8340
0.1172
0.0348
0.0047
0.0065
0.0012
0.0014
0.0002
0.0001
Ki
4.4000
0.6700
0.1750
0.0700
0.0520
0.0190
0.0146
0.0047
0.0005
Tci2 R2
117882
302577
443449
539358
586006
687175
715208
831379
1070967
zi/Ki
0.190
0.175
0.199
0.067
0.125
0.063
0.098
0.036
0.126
1.078
T T100
K 3 = exp ln( K 100 ) + (ln( K 80 ) ln( K 100 )) *
T80 T100
zi
0.8340
0.1172
0.0348
0.0047
0.0065
0.0012
0.0014
0.0002
0.0001
sTcC2+ =
613.1
153.1
Ki
4.4729
0.7003
0.1873
0.0757
0.0560
0.0209
0.0165
0.0053
0.0006
R
F
xi=yi/Ki
0.1865
0.1673
0.1858
0.0618
0.1157
0.0575
0.0870
0.0316
0.1069
1.0000
4.98
Tci2 R2
117882
302577
443449
539358
586006
687175
715208
831379
1070967
xiPMi
xiPMiTci
3.523
1.535
0.272
0.377
0.087
0.104
0.014
0.007
5.918
1937.9
1021.9
199.6
288.2
72.0
87.7
13.2
7.7
3628
x
sTc
C 2+
PM
Tc i
2
n
PM
En la Fig. 23-2, Cap.23 del GPSA, el valor de la (Tc)C2+ se encuentra entre la (Tc)C2 = 90.07 F
y la (Tc)C3 = 205.92F. En la Fig. 25-11 del GPSA (graf de Hadden), se construye una curva la
cual estar entre los componentes C2 y C3, y con la (Tc)C2+ se corta la curva de unin entre el
C2 y el C3, luego este punto se une con el punto del componente C1; se traza una curva y con
la T = 5 F se corta la curva y se obtiene una Pk = 1500 lpca.
Pk
xi = zi/Ki
fw (xi)
sTc2+
Pk (Hadden)
zi/Ki = 1
Comparar
14/06/2007
Pk
fw (xi)
Ki
sTcC2+
Pk (Hadden)
y = 1
x = 1
Comparar
donde:
x
sTc C 2 + =
PM i Tc i
zi
( K i 1) V + 1
xi =
x i PM i
y i = K i xi
zi
0.8340
0.1172
0.0348
0.0047
0.0065
0.0012
0.0014
0.0002
0.0001
sTcC2+ =
649.6
189.6
Ki
4.1000
0.5100
0.1200
0.0490
0.0340
0.0120
0.0091
0.0027
0.0015
V=
xi
0.206
0.226
0.258
0.072
0.129
0.042
0.056
0.009
0.003
1.000
Tci2 R2
117882
302577
443449
539358
586006
687175
715208
831379
1070967
0.983
yi
0.845
0.115
0.031
0.004
0.004
0.001
0.001
0.000
0.000
1.000
xiPMi
xiPMiTci
3.626
7.758
3.168
7.478
2.436
4.009
0.620
0.286
29.38
1245.1
4267.3
2109.8
5492.2
1865.0
3323.3
524.7
260.8
19088
R
F
x
sTc
C 2+
PM
Tc i
2
n
PM
En la Fig. 23-2, Cap.23 del GPSA, el valor de la (Tc)C2+ se encuentra entre la (Tc)C2 = 90.07 F
y la (Tc)C3 = 205.92F. En la Fig. 25-11 del GPSA (graf de Hadden), se construye una curva la
cual estar entre los componentes C2 y C3, y con la (Tc)C2+ se corta la curva de unin entre el
C2 y el C3, luego este punto se une con el punto del componente C1; se traza una curva y con
la T = -20 F se corta la curva y se obtiene una Pk = 1500 lpca.
Pk
Ki
fw (xi)
sTcC2+
Pk (Hadden)
y = 1
x = 1
Comparar
14/06/2007
Fase gaseosa
Temp =
presin =
C7+ =
-20.0
400
0.73
Comp
C1
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
yi
0.8448
0.1153
0.0310
0.0035
0.0044
0.0005
0.0005
0.0000
0.0000
sTr =
sPr =
1.155
0.598
F
Lpca
PMi
16.04
30.07
44.10
58.12
58.12
72.15
72.15
86.18
122.00
hi
218.2
131.6
110.1
103.6
110.1
103.6
106.1
93.5
88.1
yiPMihi
2957.2
456.2
150.3
21.2
28.0
3.8
3.9
0.2
0.1
3620.8
(0)
H H P ,T
R sTc
(I )
H H P ,T
R sTc
yiTci
290.1
63.4
20.6
2.6
3.3
0.4
0.4
0.0
0.0
380.9
0.50
0.23
H H P ,T
H H P ,T
+ w
= R sTc
R sTc
R sTc
=
382.89 Btu/Lbmol
Hp , t = Hm H H P ,T
(0 )
H H P ,T
H H P ,T
Hp,t =
3237.9
(I )
yiPci
563.5
81.6
19.0
1.9
2.4
0.2
0.2
0.0
0.0
668.9
yiwi
0.00912
0.01121
0.00469
0.00065
0.00087
0.00011
0.00013
0.00001
0.00000
0.02679
PMiewi
16.217
33.140
51.310
69.949
70.857
90.681
92.735
184.144
Grafico
TciHi0.5/PMi
316.1
209.9
158.5
128.6
138.2
116.9
120.7
79.6
Btu/Lbmol
Fase Liquida
Temp =
presin =
C7+ =
Comp
C1
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
-20.0
400
0.73
xi
0.2061
0.2260
0.2580
0.0718
0.1287
0.0419
0.0556
0.0086
0.0033
F
Lpca
PMi
16.04
30.07
44.10
58.12
58.12
72.15
72.15
86.18
122.00
hi
218.2
131.6
110.1
103.6
110.1
103.6
106.1
93.5
88.1
xiPMihi
721.3
894.6
1252.6
432.7
823.4
313.3
425.4
69.3
35.7
4968.2
xiTci
70.7
124.3
171.8
52.8
98.5
34.7
47.0
7.8
3.4
611.2
xiPci
137.4
160.0
158.7
37.9
70.6
20.6
27.1
3.8
1.2
617.3
xiwi
0.00223
0.02197
0.03909
0.01331
0.02549
0.00958
0.01395
0.00257
0.00137
0.12954
14/06/2007
sTr =
sPr =
0.720
0.648
H H P ,T
R sTc
(0)
H H P ,T
R sTc
(I )
4.70
6.60
H H P ,T
H H P ,T
+ w
= R sTc
R sTc
R sTc
=
6742.44 Btu/Lbmol
Hp , t = Hm H H P ,T
(0 )
H H P ,T
H H P ,T
Hp,t =
(I )
-1774.2 Btu/Lbmol
H Mezcla = H V V + H L L
Hmezcla =
3153.1
Btu/Lbmol
Fase gaseosa
Temp =
Presin =
-20
400
Comp
C1
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
yi
0.8448
0.1153
0.0310
0.0035
0.0044
0.0005
0.0005
0.0000
0.0000
sTr =
sPr =
F
Lpca
PMi
16.043
30.070
44.097
58.123
58.123
72.150
72.150
86.177
122.00
si
3.004
1.923
1.514
1.284
1.224
1.154
1.136
1.095
1.068
S S P ,T
1.1552
0.5980
S S P ,T
yiPMisi
40.71
6.67
2.07
0.26
0.31
0.04
0.04
0.00
0.00
50.1
yilnyi
-0.142
-0.249
-0.108
-0.020
-0.024
-0.004
-0.004
0.000
0.000
-0.551
yiTci
290.1
63.4
20.6
2.6
3.3
0.4
0.4
0.0
0.0
380.9
S S P ,T
S S P ,T
Sp,t =
51.20
0.28
Grafico
Tc.ln(PM)/ln(Tbn)
(I )
0.21
180
322
418
485
502
564
572
Ln(PM).ln(1/w).S
37.746
15.258
10.821
8.796
8.053
7.289
6.718
Btu/Lbmol R
S S P ,T
S S P ,T
+ w
= R
R
R
= 7.13 Btu/Lbmol R
(0 )
44.069
yiwi
0.00912
0.01121
0.00469
0.00065
0.00087
0.00011
0.00013
0.00001
0.00000
0.02679
(0)
Sm = Yi Si PMi R Yi Ln (Yi )
Sm =
yiPci
563.5
81.6
19.0
1.9
2.4
0.2
0.2
0.0
0.0
668.9
(I )
+ Ln ( P / 14 .7 )
Btu/Lbmol R
14/06/2007
Fase Liquida
Temp =
Presin =
-20
400
Comp
C1
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
xi
0.2061
0.2260
0.2580
0.0718
0.1287
0.0419
0.0556
0.0086
0.0033
sTr =
sPr =
F
Lpca
PMi
16.043
30.070
44.097
58.123
58.123
72.150
72.150
86.177
122.00
0.7199
0.6480
si
3.004
1.923
1.514
1.284
1.224
1.154
1.136
1.095
1.068
xiPMisi
9.93
13.07
17.23
5.36
9.16
3.49
4.55
0.81
0.43
64.0
S S P ,T
(0)
S S P ,T
(I )
xilnxi
-0.325
-0.336
-0.350
-0.189
-0.264
-0.133
-0.161
-0.041
-0.019
-1.818
4.70
7.10
xiTci
70.7
124.3
171.8
52.8
98.5
34.7
47.0
7.8
3.4
611.2
xiPci
137.4
160.0
158.7
37.9
70.6
20.6
27.1
3.8
1.2
617.3
xiwi
0.00223
0.02197
0.03909
0.01331
0.02549
0.00958
0.01395
0.00257
0.00137
0.12954
Sm = Yi Si PMi R Yi Ln (Yi )
Sm =
S S P ,T
S S P ,T
Sp,t =
67.65
Btu/Lbmol R
S S P ,T ( 0 )
S S P ,T
=
R
+ w
R
R
= 17.72 Btu/Lbmol R
49.924
(I )
+ Ln ( P / 14 .7 )
Btu/Lbmol R
S Mezcla = S V V + S L L
Smezcla =
44.168
Btu/Lbmol R
Pk
fw (xi)
Ki
sTcC2+
Pk (Hadden)
y = 1
x = 1
Comparar
donde:
x
sTc C 2 + =
PM i Tc i
xi =
2
n
x i PM i
zi
( K i 1) V + 1
y i = K i xi
14/06/2007
zi
0.8340
0.1172
0.0348
0.0047
0.0065
0.0012
0.0014
0.0002
0.0001
sTcC2+ =
682.7
222.7
Ki
3.8000
0.3900
0.0800
0.0350
0.0220
0.0075
0.0051
0.0012
0.0001
V=
xi
0.227
0.280
0.283
0.058
0.096
0.022
0.028
0.004
0.001
1.000
Tci2 R2
117882.4
302577
443449.4
539358
586005.6
687174.7
715208.5
831379.2
1070967
0.953
yi
0.864
0.109
0.023
0.002
0.002
0.000
0.000
0.000
0.000
1.000
xiPMi
xiPMiTci
8.419
12.489
3.399
5.572
1.616
2.015
0.303
0.160
33.974
4631.3
8316.8
2496.4
4265.3
1339.5
1704.3
276.4
165.4
23195
R
F
x
sTc
C 2+
PM
Tc i
PM
En la Fig. 23-2, Cap.23 del GPSA, el valor de la (Tc)C2+ se encuentra entre la (Tc)C3 = 205.92 F
y la (Tc)iC4 = 274.41F. En la Fig. 25-11 del GPSA (graf de Hadden), se construye una curva la
cual estar entre los componentes C2 y C3, y con la (Tc)C2+ se corta la curva de unin entre el
C3 y el CiC4 luego este punto se une con el punto del componente C1; se traza una curva y con
la T = -40 F se corta la curva y se obtiene una Pk = 1500 lpca.
Pk
fw (xi)
Ki
sTcC2+
Pk (Hadden)
y = 1
x = 1
Comparar
Fase gaseosa
Temp =
presin =
C7+ =
Comp
C1
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
-40.0
400
0.73
yi
0.8637
0.1092
0.0227
0.0020
0.0021
0.0002
0.0001
0.0000
0.0000
F
Lpca
PMi
16.04
30.07
44.10
58.12
58.12
72.15
72.15
86.18
122.00
hi
207.8
124.2
103.2
96.7
103.2
96.7
99.2
87.0
81.5
yiPMihi
2879.8
407.9
103.2
11.5
12.7
1.2
1.0
0.0
0.0
3417.3
yiTci
296.5
60.1
15.1
1.5
1.6
0.1
0.1
0.0
0.0
375.1
yiPci
576.1
77.3
13.9
1.1
1.2
0.1
0.1
0.0
0.0
669.7
yiwi
0.00933
0.01061
0.00343
0.00038
0.00042
0.00004
0.00004
0.00000
0.00000
0.02425
14/06/2007
sTr =
sPr =
(0)
H H P ,T
R sTc
(I )
H H P ,T
R sTc
1.120
0.597
0.55
0.26
H H P ,T ( 0 )
H H P ,T
+ w
= R sTc
R
sTc
R sTc
=
414.38 Btu/Lbmol
Hp , t = Hm H H P ,T
H H P ,T
H H P ,T
Hp,t =
3002.9
(I )
PMiewi
16.217
33.140
51.310
69.949
70.857
90.681
92.735
184.144
Grafico
TciHi0.5/PMi
308.5
203.9
153.4
124.3
133.8
113.0
116.8
76.6
Btu/Lbmol
Fase Liquida
Temp =
presin =
C7+ =
Comp
C1
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
sTr =
sPr =
-40.0
400
0.73
xi
0.2273
0.2800
0.2832
0.0585
0.0959
0.0224
0.0279
0.0035
0.0013
F
Lpca
PMi
16.04
30.07
44.10
58.12
58.12
72.15
72.15
86.18
122.00
0.7195
0.6308
hi
207.8
124.2
103.2
96.7
103.2
96.7
99.2
87.0
81.5
xiPMihi
757.8
1046.0
1289.4
328.9
575.3
156.3
200.0
26.4
13.0
4393.1
H H P ,T
R sTc
(0)
H H P ,T
R sTc
(I )
xiTci
78.0
154.0
188.6
43.0
73.4
18.6
23.6
3.2
1.4
583.7
4.77
6.80
H H P ,T ( 0 )
H H P ,T
=
R
sTc
+ w
R
sTc
R sTc
=
6445.31 Btu/Lbmol
Hp , t = Hm H H P ,T
H H P ,T
H H P ,T
Hp,t =
(I )
xiPci
151.6
198.2
174.2
30.9
52.6
11.0
13.6
1.5
0.5
634.1
xiwi
0.00245
0.02722
0.04291
0.01083
0.01899
0.00512
0.00701
0.00105
0.00054
0.11612
-2052.2 Btu/Lbmol
H Mezcla = H V V + H L L
Hmezcla =
2767.3
Btu/Lbmol
14/06/2007
Fase gaseosa
Temp =
Presin =
-40
400
Comp
C1
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
yi
0.8637
0.1092
0.0227
0.0020
0.0021
0.0002
0.0001
0.0000
0.0000
sTr =
sPr =
F
Lpca
PMi
16.043
30.070
44.097
58.123
58.123
72.150
72.150
86.177
122.00
si
2.980
1.906
1.498
1.268
1.209
1.139
1.121
1.080
1.052
S S P ,T
1.1198
0.5973
S S P ,T
yiPMisi
41.29
6.26
1.50
0.15
0.15
0.01
0.01
0.00
0.00
49.4
yilnyi
-0.127
-0.242
-0.086
-0.013
-0.013
-0.001
-0.001
0.000
0.000
-0.483
yiTci
296.5
60.1
15.1
1.5
1.6
0.1
0.1
0.0
0.0
375.1
S S P ,T
S S P ,T
Sp,t =
50.33
0.34
Grafico
Tc.ln(PM)/ln(Tbn)
(I )
0.27
Ln(PM).ln(1/w).S
180
322
418
485
502
564
572
37.448
15.123
10.707
8.685
7.950
7.189
6.629
xiPci
151.6
198.2
174.2
30.9
52.6
11.0
13.6
1.5
0.5
634.1
xiwi
0.00245
0.02722
0.04291
0.01083
0.01899
0.00512
0.00701
0.00105
0.00054
0.11612
Btu/Lbmol R
S S P ,T
S S P ,T
+ w
= R
R
R
= 7.24 Btu/Lbmol R
(0 )
43.089
yiwi
0.00933
0.01061
0.00343
0.00038
0.00042
0.00004
0.00004
0.00000
0.00000
0.02425
(0)
Sm = Yi Si PMi R Yi Ln (Yi )
Sm =
yiPci
576.1
77.3
13.9
1.1
1.2
0.1
0.1
0.0
0.0
669.7
(I )
+ Ln ( P / 14 .7 )
Btu/Lbmol R
Fase Liquida
Temp =
Presin =
-40
400
Comp
C1
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
xi
0.2273
0.2800
0.2832
0.0585
0.0959
0.0224
0.0279
0.0035
0.0013
F
Lpca
PMi
16.043
30.070
44.097
58.123
58.123
72.150
72.150
86.177
122.00
si
2.980
1.906
1.498
1.268
1.209
1.139
1.121
1.080
1.052
xiPMisi
10.87
16.05
18.71
4.31
6.73
1.84
2.26
0.33
0.17
61.3
xilnxi
-0.337
-0.356
-0.357
-0.166
-0.225
-0.085
-0.100
-0.020
-0.009
-1.655
xiTci
78.0
154.0
188.6
43.0
73.4
18.6
23.6
3.2
1.4
583.7
14/06/2007
sTr =
sPr =
0.7195
0.6308
S S P ,T
(0)
S S P ,T
(I )
4.75
7.20
Sm = Yi Si PMi R Yi Ln (Yi )
Sm =
64.55
S S P ,T
S S P ,T
Sp,t =
Btu/Lbmol R
S S P ,T ( 0 )
S S P ,T
+ w
= R
R
R
= 17.65 Btu/Lbmol R
46.898
(I )
+ Ln ( P / 14 .7 )
Btu/Lbmol R
S Mezcla = S V V + S L L
Smezcla =
43.266
Btu/Lbmol R
Pk
fw (xi)
Ki
sTcC2+
Pk (Hadden)
y = 1
x = 1
Comparar
donde:
x
sTc C 2 + =
PM i Tc i
xi =
2
n
x PM
i
zi
( K i 1) V + 1
y i = K i xi
zi
0.8340
0.1172
0.0348
0.0047
0.0065
0.0012
0.0014
0.0002
0.0001
sTcC2+ =
681.0
221.0
Ki
3.7000
0.2850
0.0550
0.0235
0.0150
0.0042
0.0028
0.0005
0.0000
R
F
V=
xi
0.239
0.343
0.267
0.046
0.069
0.014
0.018
0.002
0.001
1.000
Tci2 R2
117882
302577
443449
539358
586006
687175
715208
831379
1070967
0.921
yi
0.885
0.098
0.015
0.001
0.001
0.000
0.000
0.000
0.000
1.000
xiPMi
xiPMiTci
5.498
8.043
2.040
4.036
0.839
1.264
0.152
0.066
21.94
3024.5
5355.7
1497.9
3089.5
695.9
1068.8
138.2
68.6
14939
x
sTc
C 2+
PM
Tc i
2
n
PM
14/06/2007
En la Fig. 23-2, Cap.23 del GPSA, el valor de la (Tc)C2+ se encuentra entre la (Tc)C3 = 205.92 F
y la (Tc)iC4 = 274.41F. En la Fig. 25-11 del GPSA (graf de Hadden), se construye una curva la
cual estar entre los componentes C2 y C3, y con la (Tc)C2+ se corta la curva de unin entre el
C3 y el CiC4 luego este punto se une con el punto del componente C1; se traza una curva y con
la T = -60 F se corta la curva y se obtiene una Pk = 1500 lpca.
Pk
fw (xi)
Ki
sTcC2+
Pk (Hadden)
y = 1
x = 1
Comparar
Fase gaseosa
Temp =
presin =
C7+ =
-60.0
400
0.73
Comp
C1
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
yi
0.8854
0.0977
0.0147
0.0011
0.0010
0.0001
0.0000
0.0000
0.0000
sTr =
sPr =
1.083
0.597
F
Lpca
PMi
16.04
30.07
44.10
58.12
58.12
72.15
72.15
86.18
122.00
hi
197.6
117.0
96.6
90.1
96.6
90.1
92.6
80.8
75.2
yiPMihi
2806.4
343.8
62.7
5.7
5.8
0.4
0.3
0.0
0.0
3225.1
H H P ,T
R sTc
(0)
H H P ,T
R sTc
(I )
yiTci
304.0
53.7
9.8
0.8
0.8
0.1
0.0
0.0
0.0
369.2
0.60
0.34
H H P ,T ( 0 )
H H P ,T
=
R
sTc
+ w
sTc
R sTc
=
445.35 Btu/Lbmol
Hp , t = Hm H H P ,T
H H P ,T
H H P ,T
Hp,t =
2779.8
(I )
yiPci
590.5
69.1
9.0
0.6
0.6
0.0
0.0
0.0
0.0
669.9
yiwi
0.00956
0.00949
0.00223
0.00020
0.00021
0.00001
0.00001
0.00000
0.00000
0.02172
PMiewi
16.217
33.140
51.310
69.949
70.857
90.681
92.735
184.144
Grafico
TciHi0.5/PMi
300.8
197.9
148.4
119.9
129.4
109.1
112.8
73.5
Btu/Lbmol
14/06/2007
Fase Liquida
Temp =
presin =
C7+ =
-60.0
400
0.73
Comp
C1
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
xi
0.2393
0.3427
0.2675
0.0463
0.0694
0.0144
0.0175
0.0021
0.0008
sTr =
sPr =
0.707
0.619
F
Lpca
PMi
16.04
30.07
44.10
58.12
58.12
72.15
72.15
86.18
122.00
hi
197.6
117.0
96.6
90.1
96.6
90.1
92.6
80.8
75.2
xiPMihi
758.5
1206.3
1139.2
242.2
389.8
93.9
117.0
14.6
7.1
3968.5
H H P ,T
R sTc
(0)
H H P ,T
R sTc
(I )
xiTci
82.2
188.5
178.1
34.0
53.2
12.0
14.8
1.9
0.8
565.4
4.77
6.80
H H P ,T
H H P ,T
+ w
= R sTc
R sTc
R sTc
=
6176.21 Btu/Lbmol
Hp , t = Hm H H P ,T
(0 )
H H P ,T
H H P ,T
Hp,t =
(I )
xiPci
159.6
242.6
164.5
24.4
38.1
7.1
8.5
0.9
0.3
646.0
xiwi
0.00258
0.03331
0.04052
0.00857
0.01376
0.00330
0.00440
0.00063
0.00032
0.10738
-2207.7 Btu/Lbmol
H Mezcla = H V V + H L L
Hmezcla =
2383.3
Btu/Lbmol
Fase gaseosa
Temp =
Presin =
-60
400
Comp
C1
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
yi
0.8854
0.0977
0.0147
0.0011
0.0010
0.0001
0.0000
0.0000
0.0000
F
Lpca
PMi
16.043
30.070
44.097
58.123
58.123
72.150
72.150
86.177
122.00
si
2.955
1.889
1.482
1.251
1.193
1.122
1.106
1.065
1.036
yiPMisi
41.98
5.55
0.96
0.08
0.07
0.00
0.00
0.00
0.00
48.6
yilnyi
-0.108
-0.227
-0.062
-0.007
-0.007
-0.001
0.000
0.000
0.000
-0.413
yiTci
304.0
53.7
9.8
0.8
0.8
0.1
0.0
0.0
0.0
369.2
yiPci
590.5
69.1
9.0
0.6
0.6
0.0
0.0
0.0
0.0
669.9
yiwi
0.00956
0.00949
0.00223
0.00020
0.00021
0.00001
0.00001
0.00000
0.00000
0.02172
14/06/2007
sTr =
sPr =
S S P ,T
1.0834
0.5971
S S P ,T
(0)
0.38
Grafico
Tc.ln(PM)/ln(Tbn)
(I )
0.32
Sm = Yi Si PMi R Yi Ln (Yi )
Sm =
S S P ,T
S S P ,T
Sp,t =
49.46
37.138
14.984
10.591
8.573
7.846
7.088
6.539
xiPci
159.6
242.6
164.5
24.4
38.1
7.1
8.5
0.9
0.3
646.0
xiwi
0.00258
0.03331
0.04052
0.00857
0.01376
0.00330
0.00440
0.00063
0.00032
0.10738
Btu/Lbmol R
S S P ,T ( 0 )
S S P ,T
+ w
= R
R
R
= 7.33 Btu/Lbmol R
42.134
Ln(PM).ln(1/w).S
180
322
418
485
502
564
572
(I )
+ Ln ( P / 14 .7 )
Btu/Lbmol R
Fase Liquida
Temp =
Presin =
-60
400
Comp
C1
C2
C3
iC4
nC4
iC5
nC5
nC6
C7+
xi
0.2393
0.3427
0.2675
0.0463
0.0694
0.0144
0.0175
0.0021
0.0008
sTr =
sPr =
F
Lpca
PMi
16.043
30.070
44.097
58.123
58.123
72.150
72.150
86.177
122.00
#REF!
0.6192
si
2.955
1.889
1.482
1.251
1.193
1.122
1.106
1.065
1.036
xiPMisi
11.34
19.46
17.48
3.36
4.81
1.17
1.40
0.19
0.10
59.3
S S P ,T
(0)
S S P ,T
(I )
xilnxi
-0.342
-0.367
-0.353
-0.142
-0.185
-0.061
-0.071
-0.013
-0.006
-1.540
4.55
5.30
xiTci
#REF!
188.5
178.1
34.0
53.2
12.0
14.8
1.9
0.8
#REF!
Sm = Yi Si PMi R Yi Ln (Yi )
Sm =
S S P ,T
S S P ,T
Sp,t =
62.38
Btu/Lbmol R
(I )
S S P ,T ( 0 )
S S P ,T
+ w
+ Ln ( P / 14 .7 )
= R
R
R
= 16.73 Btu/Lbmol R
45.656
Btu/Lbmol R
S Mezcla = S V V + S L L
Smezcla =
42.414
Btu/Lbmol R
14/06/2007
Con las entropas obtenidas a las distintas temperaturas sern utilizadas para graficar
T vs S donde entraremos con la entropa de entrada (S 2 = S 1 ) y obtendremos la
temperatura de salida en el turbo-expansor (isoentropico)
T
F
-20
-40
-60
Stotal
Btu/LbmolF
44.168
43.266
42.414
Htotal
Btu/Lbmol
3153.1
2767.3
2383.3
h2
real
= ( h2 h1 ) is + h1
H2 real =
2877.692 Btu/Lbmol
W
W
max
max
= m (h2 h1 )
-7212
hp
real
real
-5914
h1 )
hp
14/06/2007
Entrada Turbo-expansor
T = 20F P = 800 Lpca
2
Ki vs Tc
10.0000
Ki
1.0000
0.1000
y = 6.262348E+00e-7.766982E-06x
R2 = 9.982822E-01
0.0100
0.0010
0
100000
200000
300000
400000
500000
Tc2
600000
700000
800000
900000
Entrada Turbo-expansor
T = 20F P = 800 Lpca
Tci.Ln(PMi)/Ln(Tbni) vs Si.Ln(PMi).ln(1/wi)
Si.Ln(PMi).ln(1/wi))
100
10
y = 7.028338E+04x-1.451188E+00
R2 = 9.978140E-01
1
100
1000
Tci.Ln(PMi)/Ln(Tbni)
Entrada Turbo-expansor
T = 20F P = 800 Lpca
PMi.ewi vs Tci.Hi0.5/PMi
1000
100
Tci.Hi0.5/PMi
y = 1.534315E+03x-5.551037E-01
R2 = 9.950624E-01
10
1
10
100
PMi.ewi
1000
Salida Turbo-expansor
44.4
44.2
44
43.8
43.6
43.4
43.2
43
42.8
42.6
42.4
42.2
-70
-60
-50
-40
-30
Tsalida, F
-20
-10
Salida Turbo-expansor
3500
3000 H2 real
2500
H2 ideal
2000
1500
1000
500
Tideal
Treal
0
-70
-60
-50
-40
-30
Tsalida, F
-20
-10