SISTEMA METANOL AGUA

Compuesto PM Cpi (cal/mol°C) Calor Latente (cal/mol)

Metanol (A) 32.04000 19.3842 8415

Agua (B) 18.01500 17.9970 9718
Datos Temperatura (°C) Densidad (g/cm3) índice de R.
25.00000 0.96000 -
Alimentacion
25.00000 0.97700 1.33600
Destilado - 0.80500 1.33280
Plato 8 - 0.96800 1.33750
Plato 9 - 0.96800 1.33751
Plato 10 - 0.97700 1.33600
Residuo - 0.99600 1.33300
Reflujo - 0.80500 1.33280

Constantes de los Rotámetros

(L/min) al 100%
Alimentación 4.50000
Residuo 1.64000
Destilado 1.01000
Reflujo 1.64000

Corriente Tburbuja Trocío

Alimentación 77.17043 89.25291
Destilado 59.58163
- Reflujo 59.58163
Residuo 91.30000
OL AGUA

Xw Xn % Rotámetro Gasto (L/min)

0.23000 0.14380
20.00000 0.90000
0.11000 0.06498
0.94000 0.89805 11.00000 0.11110
0.17500 0.10656 - C -
0.17500 0.10656 - Á -
0.11000 0.06498 - L -
C
0.01000 0.00565 5.00000 U 0.08200
0.94000 0.89805 30.00000 L 0.49200
O
S
D. Flotador ( g/cm3)

8.02000

Diagrama T vs X-Y (mezcla metanol-agua) @ 585 mm de Hg

NO IDEAL
93

88

Tfba=77.17043 °C

TfRa=85.25291 °C
83
Tdestilado=59.58163
°C

Tresiduo=91.3 °C
Temperatura, T (°C)

78

73

68

63

58
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
68

63

58
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

Fracción molar x, y
 Gasto corregido (L/min) Flujo Másico (Kg/h) PMpromedio Flujo Molar (Kmol/h)

0.92117 53.05950 20.03178 2.64877

0.12554 6.06335311400 30.61017 0.19808

- - - -
- - - -
- - - -
0.08219 4.91155 18.09420 0.27144
0.55593 26.85121 30.61017 0.87720

Diagrama X vs Y (mezcla Metano

a) @ 585 mm de Hg NO IDEA
1.0

0.9

0.8

Tfba=77.17043 °C

TfRa=85.25291 °C 0.7
Fracción molar del vapor, y

Tdestilado=59.58163
°C
0.6
Tresiduo=91.3 °C

0.5

0.4

0.3

0.2

0.1

0.0
0.0 0.1 0.2 0.3
0.6 0.7 0.8 0.9 1.0
 0.2

0.1

0.0
0.0 0.1 0.2 0.3
0.6 0.7 0.8 0.9 1.0

y
 Cp prom (cal/mol°C) Temperatura (°C) Lambda de mezcla (cal/mol) Entalpía (Kcal/Kmol°C)
hf 35.00000 - 636.87626
hf L.S. 18.19646 77.17043 - 1,404.22892
Hf R. 89.25291 9,530.63037 11,154.71786
hD 19.24277 59.58163 - 1,146.51589
- - - -
- - - -
- - - -
hw 18.00482 91.30000 - 1,643.83999
h1 19.24277 59.58163 - 1,146.51589

a X vs Y (mezcla Metanol-agua) @ 585 mm de Hg

NO IDEAL

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Fracción molar del líquido, x
 La relación Boilup y puntos de intersección se calcularon igualando rectas LOZE=LOZA=ALIM

Puntos para graficar

Línea de Operación Alimentación x
0.14380
q 1.07870
0.15458

Línea de Operación LOZE

R 4.42844 0.89805
Rint 0.81579 0.15458

Línea de Operación LOZA 0.00565

s 1.16987 0.15458

0.9 1.0
0.9 1.0
o rectas LOZE=LOZA=ALIM

Puntos para graficar

y
0.14382
0.29154

0.89805
0.29154

0.00565
0.29154
.
 Calculos para diagramas T vs X-Y y X vs Y no ideales para
Pman (Hg) 0 Patm (Hg) 585 PTOT (Hg) 585

(g/mol) (cal/g°C) (cal/mol°C) VanLaar (cal/mol)

Compuesto PM Cp A12_21 l
Metanol (1) 32.04 0.605 19.3842 0.9014 8415
Agua (2) 18.015 0.999 17.9970 0.5559 9718

Ec. Antoine Ec. Van Laar Raoult m

(°C) (mm Hg) (-) (-) (-) (mm Hg) (-)
Ti P1 i
0
P2 i
0
X1_supuesta g1 g2 P X1_calculada
58.074 585 136.5905 1.00000 1.00000 1.74351 584.99931 1.00000
59.012 607.9473 142.7180 0.94404 1.00112 1.67763 587.96877 0.93600
59.950 631.6421 149.0778 0.87996 1.00544 1.60476 587.56258 0.87349
60.888 656.1033 155.6770 0.81766 1.01326 1.53666 587.20428 0.81248
61.826 681.3503 162.5227 0.75721 1.02487 1.47329 586.89231 0.75309
62.764 707.4026 169.6223 0.69871 1.04058 1.41464 586.62221 0.69544
63.702 734.2802 176.9833 0.64231 1.06068 1.36071 586.39310 0.63972
64.640 762.0032 184.6136 0.58818 1.08543 1.31149 586.19593 0.58614
65.578 790.5923 192.5208 0.53654 1.11504 1.26698 586.02814 0.53493
66.516 820.0685 200.7131 0.48762 1.14955 1.22713 585.88382 0.48635
67.454 850.4528 209.1987 0.44165 1.18887 1.19186 585.75975 0.44065
68.392 881.767 217.9858 0.39881 1.23272 1.16101 585.64583 0.39804
69.331 914.033 227.0831 0.35925 1.28058 1.13435 585.55067 0.35865
70.269 947.273 236.4992 0.32298 1.33185 1.11155 585.45383 0.32253
71.207 981.5096 246.2431 0.28996 1.38577 1.09223 585.35785 0.28963
72.145 1016.766 256.3237 0.26006 1.44158 1.07601 585.26331 0.25984
73.083 1053.065 266.7502 0.23306 1.49859 1.06244 585.15065 0.23294
74.021 1090.43 277.5322 0.20875 1.55608 1.05117 585.03971 0.20872
74.959 1128.886 288.6791 0.18685 1.61356 1.04181 584.90652 0.18691
75.897 1168.457 300.2007 0.16711 1.67058 1.03407 584.75113 0.16726
76.835 1209.167 312.1070 0.14930 1.72677 1.02766 584.58500 0.14953
77.773 1251.042 324.4080 0.13319 1.78189 1.02236 584.39880 0.13351
78.711 1294.106 337.1142 0.11857 1.83580 1.01798 584.17603 0.11898
79.649 1338.386 350.2360 0.10528 1.88831 1.01437 583.94009 0.10577
80.587 1383.908 363.7841 0.09315 1.93939 1.01140 583.66648 0.09373
81.525 1430.697 377.7693 0.08205 1.98899 1.00895 583.36166 0.08271
82.463 1478.781 392.2028 0.07187 2.03706 1.00694 583.04048 0.07262
83.401 1528.188 407.0957 0.06250 2.08362 1.00530 582.68674 0.06333
84.339 1578.943 422.4596 0.05385 2.12871 1.00398 582.29518 0.05477
85.277 1631.076 438.3061 0.04585 2.17231 1.00291 581.88231 0.04685
86.215 1684.614 454.6470 0.03842 2.21454 1.00206 581.41153 0.03952
87.153 1739.586 471.4944 0.03151 2.25539 1.00140 580.90305 0.03270
88.091 1796.021 488.8605 0.02508 2.29482 1.00089 580.39336 0.02635
89.029 1853.948 506.7578 0.01906 2.33305 1.00052 579.79806 0.02042
89.967 1913.397 525.1989 0.01344 2.36992 1.00026 579.21983 0.01488
90.905 1974.397 544.1965 0.00816 2.40566 1.00010 578.56562 0.00969
91.843 2036.979 563.7639 0.00320 2.44022 1.00001 577.87440 0.00482
92.831 2104.627 585.0000 0.000040 2.46276 1.00000 585.18393 0.00000
X vs Y no ideales para Metanol (1)-Agua(2) @ 585 mm de Hg
NOMENC

A B C (°C) (cal /mol)

Ctes. de Antoine (mm Hg y °C) p.e. hli Hvi
8.0724 1574.99 238.80 58.07418 1125.72151280678 9540.7215128
7.96681 1668.21 228.00 92.830955 1670.6772996362 11388.6773

(-) (cal °C/mol) volatilidad f (x) Referencia

y1 hl Hv K1 K2 a 1/(y-x) p/graficar
1.000001 1126 9541 1.00000 0.407088 2.45647 313890.6110 1.0000 Diagra
0.968889 1139 9597 1.03514 0.407212 2.54202 40.2434 0.9440
0.944127 1152 9645 1.08087 0.407163 2.65464 15.5843 0.8799 93
0.919852 1165 9693 1.13215 0.407391 2.77903 9.7855 0.8176
0.896038 1178 9740 1.18982 0.407985 2.91633 7.2031 0.7572
0.872656 1190 9786 1.25482 0.409046 3.06769 5.7489 0.6987
88
0.849662 1203 9832 1.32818 0.410687 3.23404 4.8227 0.6423
0.827019 1216 9878 1.41097 0.413035 3.41610 4.1869 0.5881
0.804671 1229 9923 1.50426 0.416225 3.61406 3.7295 0.5365
83
0.782557 1242 9968 1.60904 0.420392 3.82747 3.3906 0.4876
0.760610 1255 10012 1.72610 0.425663 4.05508 3.1352 0.4416
0.738761 1269 10056 1.85602 0.432145 4.29490 2.9416 0.3988

Temperatura, T (°C)
78
0.716919 1282 10101 1.99896 0.439914 4.54397 2.7959 0.3592
0.695026 1296 10145 2.15495 0.449019 4.79923 2.6878 0.3229
0.672995 1310 10189 2.32362 0.459471 5.05716 2.6107 0.2899
0.650748 1324 10234 2.50443 0.471251 5.31443 2.5596 0.2600 73
0.628232 1339 10278 2.69693 0.484332 5.56834 2.5305 0.2330
0.605357 1354 10324 2.90030 0.498656 5.81625 2.5214 0.2087
0.582082 1368 10369 3.11421 0.514184 6.05661 2.5302 0.1868 68
0.558350 1384 10415 3.33818 0.530870 6.28813 2.5560 0.1671
0.534093 1399 10462 3.57169 0.548661 6.50983 2.5988 0.1493
0.509270 1414 10509 3.81456 0.567528 6.72137 2.6590 0.1331 63
0.483848 1430 10557 4.06679 0.587455 6.92273 2.7376 0.1185
0.457763 1445 10606 4.32799 0.608402 7.11370 2.8370 0.1052
0.430990 1461 10655 4.59842 0.630377 7.29471 2.9600 0.0931
58
0.403484 1476 10705 4.87802 0.653368 7.46596 3.1111 0.0820 0.0 0.1
0.375194 1492 10756 5.16664 0.677355 7.62767 3.2968 0.0718
0.346094 1508 10808 5.46462 0.702359 7.78038 3.5262 0.0625
0.316147 1524 10861 5.77217 0.728393 7.92453 3.8125 0.0538
0.285307 1540 10915 6.08921 0.755447 8.06041 4.1761 0.0458 Dia
0.253554 1556 10970 6.41653 0.783582 8.18871 4.6483 0.0384
1.0
0.220837 1572 11025 6.75403 0.812792 8.30967 5.2819 0.0315
0.187107 1588 11082 7.10130 0.843043 8.42342 6.1718 0.0250
0.152353 1605 11141 7.46010 0.874478 8.53092 7.5023 0.0190 0.9
0.116506 1621 11200 7.82881 0.906970 8.63183 9.7025 0.0134
0.079550 1637 11260 8.20948 0.940687 8.72711 14.0076 0.0081
0.8
0.041433 1653 11322 8.60166 0.975597 8.81682 26.1551 0.0047

0.7
por, y

0.6
 0.9

0.8

0.000000 1671 11389 8.85737 0.999686 8.86016 -24998.3531

0.7

Fracción molar del vapor, y

0.6

0.5

34.7070
0.4

0.3

0.2

0.1

0.0
0.0 0.1
 585.0 mmHg = 0.8 atm = 0.7799337 bar = 0.7951 Kg/cm2

NOMENCLATURA DE COLOR

Celdas dato (llenar)

y Constantes de los componentes de la mz
y Titulos generales del proceso de cálculo
y Variables calculadas

Diagrama T vs X-Y (mezcla metanol-agua) @ 1136.8 mm de Hg

NO IDEAL
93

liquido Vapor
88

83
Temperatura, T (°C)

78

73

68

63

58
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Fracción molar x, y

Diagrama X vs Y (mezcla Metanol-agua) @ 585 mm de Hg

NO IDEAL
1.0

0.9

0.8

0.7
por, y

0.6
 0.9

0.8

0.7
Fracción molar del vapor, y

0.6

0.5

0.4

0.3

0.2

0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
Fracción molar del líquido, x
g

liquido Vapor

0.7 0.8 0.9 1.0

0.7 0.8 0.9 1.0