NAOH FEM PH PRIMERA DERIVADA SEGUNDA DERIVADA

ML MV PH Vm DmV Vm DmV/Dv
TITULANTE
0 239.4 2.87 35
1 226.9 3.09 0.5 12.5
30
2 213.7 3.31 1.5 13.2 1 0.7
3 180.4 3.88 2.5 33.3 2 20.1 25

4 152.5 4.38 3.5 27.9 3 -5.4 20

mV (FEM)
5 131.1 4.74 4.5 21.4 4 -6.5 15
6 121.3 4.96 5.5 9.8 5 -11.6
10
7 110.2 5.12 6.5 11.1 6 1.3
8 98.5 5.32 7.5 11.7 7 0.6 5

9 89.2 5.48 8.5 9.3 8 -2.4 0

0 10
10 77.1 5.76 9.5 12.1 9 2.8
11 65.5 5.97 10.5 11.6 10 -0.5
12 57.1 6.06 11.5 8.4 11 -3.2
13 43.4 6.28 12.5 13.7 12 5.3
14 25.6 6.58 13.5 17.8 13 4.1
15 9.5 6.85 14.5 16.1 14 -1.7
25
16 -17.8 7.35 15.5 27.3 15 11.2
17 -47.8 7.81 16.5 30 16 2.7 20
18 -68.2 8.16 17.5 20.4 17 -9.6 15
19 -82.7 8.4 18.5 14.5 18 -5.9

Vm DmV/Dv
10
20 -92.7 8.58 19.5 10 19 -4.5 5
21 -99.7 8.7 20.5 7 20 -3
0
22 -105.8 8.81 21.5 6.1 21 -0.9 0 1
-5
23 -111.4 8.9 22.5 5.6 22 -0.5
24 -116.4 8.99 23.5 5 23 -0.6 -10
25 -120.5 9.05 24.5 4.1 24 -0.9 -15
26 -124.2 9.12 25.5 3.7 25 -0.4
27 -127.9 9.18 26.5 3.7 26 0
28 -130.8 9.23 27.5 2.9 27 -0.8
29 -133.8 9.28 28.5 3 28 0.1
30 -136.4 9.32 29.5 2.6 29 -0.4
31 -138.9 9.36 30.5 2.5 30 -0.1
32 -141.9 9.42 31.5 3 31 0.5
33 -143.9 9.45 32.5 2 32 -1
34 -145.5 9.49 33.5 1.6 33 -0.4
35 -147.2 9.51 34.5 1.7 34 0.08
37 -150.8 9.57 36 1.8 35.25 0.05714286
39 -154.2 9.62 38 1.7 37 -0.05
41 -157.3 9.68 40 1.55 39 -0.075
43 -160.3 9.73 42 1.5 41 -0.025
45 -162.7 9.77 44 1.2 43 -0.15
47 -165.3 9.81 46 1.3 45 0.05
49 -167 9.85 48 0.85 47 -0.225
51 -167.2 9.87 50 0.1 49 -0.375
53 -169.7 9.89 52 1.25 51 -0.02254902
 PRIMERA DERIVADA METODO G
35 300
250
30
200
25 150
20 100
mV (FEM)

mV
50
15
0
0 10
10 -50
-100
5
-150
0 -200
0 10 20 30 40 50 60
mL (VOLUMEN GASTADO)

SEGUNDA DERIVADA
25
20
15
Vm DmV/Dv

10
5
0
0 10 20 30 40 50 60
-5
-10
-15
mL (VOLUMEN GASTADO)

vol. G PRIMER METODO 1RA DERIVADA 2DA DERIVADA

pto eq (ml) pto eq (ml) pto eq (ml)
1ro
2do

calculos 18 ml (Na OH) 0,021 molar (Na OH)1 mol NaH3PO4

10 ml (pepsi) 1000 ml (Na OH) 1 mol NaOH
 METODO GRAFICO (TITULANTE)
300
250
200
150
100
50
0
0 10 20 30 40 50 60
-50
-100
-150
-200

mL (VOLUMEN GASTADO)
NAOH PH PRIMERA DERIVADA SEGUNDA DERIVADA
ML PH Vm DpH/Dv Vm DpH/Dv
TITULANTE
0 2.87
1 3.09 0.5 -0.22
2 3.31 1.5 -0.22 1 -4.440892E-16
3 3.88 2.5 -0.57 2 -0.35
4 4.38 3.5 -0.5 3 0.07
5 4.74 4.5 -0.36 4 0.14
6 4.96 5.5 -0.22 5 0.14
7 5.12 6.5 -0.16 6 0.06
8 5.32 7.5 -0.2 7 -0.04
9 5.48 8.5 -0.16 8 0.04
10 5.76 9.5 -0.28 9 -0.12
11 5.97 10.5 -0.21 10 0.07
12 6.06 11.5 -0.09 11 0.12 12
13 6.28 12.5 -0.22 12 -0.13
10
14 6.58 13.5 -0.3 13 -0.08
15 6.85 14.5 -0.27 14 0.03 8

16 7.35 15.5 -0.5 15 -0.23 6

pH
17 7.81 16.5 -0.46 16 0.04
4
18 8.16 17.5 -0.35 17 0.11
19 8.4 18.5 -0.24 18 0.11 2

20 8.58 19.5 -0.18 19 0.06 0

0 10 2
21 8.7 20.5 -0.12 20 0.06
22 8.81 21.5 -0.11 21 0.01 mL
23 8.9 22.5 -0.09 22 0.02
24 8.99 23.5 -0.09 23 0
25 9.05 24.5 -0.06 24 0.03
26 9.12 25.5 -0.07 25 -0.01
27 9.18 26.5 -0.06 26 0.01 PR
28 9.23 27.5 -0.05 27 0.01
0
29 9.28 28.5 -0.05 28 1.7763568E-15 0 10
30 9.32 29.5 -0.04 29 0.01 -0.1

31 9.36 30.5 -0.04 30 1.7763568E-15 -0.2

pH(FEM)

32 9.42 31.5 -0.06 31 -0.02

-0.3
33 9.45 32.5 -0.03 32 0.03
34 9.49 33.5 -0.04 33 -0.01 -0.4
35 9.51 34.5 -0.02 34 0.016 -0.5
37 9.57 36 -0.03 35.25 -0.0057142857
-0.6
39 9.62 38 -0.025 37 0.0025
41 9.68 40 -0.03 39 -0.0025 m
43 9.73 42 -0.025 41 0.0025
45 9.77 44 -0.02 43 0.0025
47 9.81 46 -0.02 45 -4.440892E-16
49 9.85 48 -0.02 47 4.4408921E-16
51 9.87 50 -0.01 49 0.005
53 9.89 52 -0.01 51 1.7415263E-17
 TITULANTE
12

10
SEGUNDA DERIVA
8 0.2
6
pH

0.1
4
0

Vm DpH/Dv
2 0 10 20 30
-0.1
0
0 10 20 30 40 50 60
-0.2
mL (VOLUMEN GASTADO)
-0.3

-0.4
mL (VOLUMEN GAST

PRIMERA DERIVADA
0
0 10 20 30 40 50 60
-0.1

-0.2
pH(FEM)

-0.3

-0.4

-0.5

-0.6

mL (VOLUMEN GASTADO)
 SEGUNDA DERIVADA

10 20 30 40 50 60

mL (VOLUMEN GASTADO)