Termo II Ejercicio

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Benceno Tolueno Benceno Tolueno

T( C ) PV1 (Kpa) PV2 (Kpa) X1 Y1


80.05 101.484826 38.96037319 1 1
82.05 107.885047 41.724243518 0.90084692 0.95917012
84.05 114.595924 44.64359573 0.81028617 0.91641246
86.05 121.62751 47.724676355 0.72528103 0.87060574
88.05 128.989978 50.973862219 0.64539406 0.82160736
90.05 136.693616 54.397658903 0.57022657 0.76927048
92.05 144.748821 58.00269909 0.49941484 0.71344396 Curva T-X-Y
94.05 153.166098 61.795740796 0.43262673 0.65397235 110.05

96.05 161.95605 65.783665506 0.36955863 0.59069584


105.05
98.05 171.129377 69.9734762 0.30993272 0.52345022
100.05 180.696871 74.372295285 0.25349459 0.45206691 100.05
102.05 190.669408 78.987362435 0.200011 0.37637285
104.05 201.057949 83.826032339 0.14926795 0.29619055 95.05
106.05 211.873527 88.895772361 0.10106891 0.21133804
108.05 223.127249 94.204160124 0.05523324 0.12162883 90.05
110.05 234.830291 99.758881015 0.01159475 0.02687193
85.05
110.65 238.430498 101.47449423 0 0
80.05
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.
Benceno Tolueno
A= 13.7819 A= 13.932
B= 2726.81 B= 3056.96
C= 217.572 C= 217.625

Presion total (Kpa)= 101.325

Curva T-X-Y Curva Y Vs X


1
0.9
0.8
0.7
Benceno 0.6
Tolueno
0.5
0.4
0.3
0.2
0.1

.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0


0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.9 1
Suponiendo que la ley de Raoult es válida prepare un diagrama P-x-y para una temperatura de 90°C, y un diagrama

a) Benceno(1 )/etilbenceno(2)

Constantes de Antoine A B C Psat


T= 90 C Benceno 13.78 2726.81 217.572 136.496784
P const Etilbenceno 13.9726 3259.93 212.3 24

Benceno Etilbenceno Etilbenceno Benceno 𝑃𝑇=𝑃1𝑠𝑎𝑡∗𝑋1+𝑃2𝑠𝑎𝑡∗𝑋2


X1 X2 PT Y1 Y2
0 1 24.26 0 1 𝑌1=(𝑃𝑠𝑎𝑡∗𝑋1)/𝑃𝑇
0.1 0.9 35.48 0.38467171 0.61532829
0.2 0.8 46.71 0.58447338 0.41552662
0.3 0.7 57.93 0.70685559 0.29314441
0.4 0.6 69.15 0.78951323 0.21048677
0.5 0.5 80.38 0.8490871 0.1509129
0.6 0.4 91.60 0.89406228 0.10593772
0.7 0.3 102.83 0.92921919 0.07078081
0.8 0.2 114.05 0.9574565 0.0425435
0.9 0.1 125.27 0.98063406 0.01936594
1 0 136.50 1 0

P Vs XY
160.00

140.00

120.00

100.00 P-X1
P-Y1
80.00

60.00

40.00

20.00

0.00
0 0.2 0.4 0.6 0.8 1 1.2
atura de 90°C, y un diagrama de t-x-y para una presión de 90 kPa para uno de los sistemas siguientes

Constantes de Antoine A B C T sat


T const Benceno 13.78 2726.81 217.572 76.1991122
PT=90 kpa Etilbenceno 13.9726 3259.93 212.3 131.836193

Benceno Etilbenceno Benceno Etilbenceno 𝑋1=(𝑃𝑇−𝑃𝑠𝑎𝑡2)/(𝑃𝑠𝑎𝑡1−𝑃𝑠𝑎𝑡2)


T(C) PV1 PV2 X1 Y1
76.1991122 90 14.4830815 1 1
79.1991122 98.8536497 16.2691818 0.8927928 0.81283141
82.1991122 108.374543 18.2323012 0.79616057 0.66117419 Ch
85.1991122 118.596118 20.385409 0.70882893 0.53791477 131.4
88.1991122 129.552433 22.7420403 0.6296949 0.43744868
91.1991122 141.278143 25.3162965 0.5578016 0.35534261 111.4
94.1991122 153.808454 28.1228452 0.49231694 0.288076
97.1991122 167.179095 31.1769184 0.43251574 0.23284261 91.4
100.199112 181.426276 34.4943094 0.37776457 0.18739739
103.199112 196.586657 38.0913691 0.32750898 0.14993799 71.4
106.199112 212.697307 41.9850014 0.28126267 0.11901251
109.199112 229.795668 46.1926565 0.23859818 0.09344752 51.4
112.199112 247.919516 50.7323245 0.19913908 0.07229167
115.199112 267.106928 55.6225272 0.16255323 0.05477129 31.4
118.199112 287.396239 60.8823092 0.12854702 0.04025534
121.199112 308.826008 66.531228 0.09686041 0.02822766 11.4
124.199112 331.434981 72.5893434 0.0672627 0.01826495
127.199112 355.262055 79.0772063 0.03954885 0.01001907 0 0.1 0.2 0.3 0.4
-8.59999999999999
130.199112 380.346238 86.0158459 0.01353633 0.00320306
131.836193 394.578671 90 0 0
−𝑃𝑠𝑎𝑡2)/(𝑃𝑠𝑎𝑡1−𝑃𝑠𝑎𝑡2)

Chart Title
131.4

111.4

91.4

Etilbenceno
71.4
Benceno

51.4

31.4

11.4

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1


99999999
k
La corriente de un pozo de gas es una mezcla con 50%mol de metano, lO%mol de etano, 20%mol
de propano y 20%mol de n-butano. Tal corriente se alimenta a un condensador parcial que se
mantiene a una presión de 250(psia), donde su temperatura resulta de 80(OF). Determine la fracción
mol del gas que se condensa las composiciones de las fases vapor líquido que dejan el
condensador.
V

𝑋𝑖=𝑍𝑖/
(1−(1−𝐾𝑖))

F Zi Ki Xi
Metano 0.5 10 0.05708745
F Etano 0.1 2.1 0.05132785
Propano 0.2 0.69 0.27293953
N-butano 0.2 0.215 0.61864519
1.00000001
T(F)= 80
P(psia)= 250

L
mol de etano, 20%mol
dor parcial que se
F). Determine la fracción
ue dejan el

∑▒ 〖 (𝑍𝑖(𝐾𝑖−1))/
𝑌𝑖=(𝐾𝑖∗𝑍𝑖)/ (1−𝜃(1−𝐾𝑖))=0 〗
(1−−𝐾𝑖))
(0,5(10−1))/(1−𝜃(1−10))+(0,1(2,1−1))/(1−𝜃(1−2,1))+(0,2(0,69−1))/
Yi (1−𝜃(1−0,69))+(0,2(0,215−1))/(1−𝜃(1−0,215))=
0.57087453
0.10778848 Resolviendo para q
0.18832827 q= 0.86205467
0.13300871
1 =𝑉/𝐹 𝐿/𝐹+𝑉/𝐹=1 𝐿/𝐹=1−0,8620=0,138
0,69−1))/
-1.3489E-08

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