CONSTANTES CRTICAS, CONSTANTES DE Cp/R = a + bT + cT2 + d/T2, ENTALPA DE FORMACIN

ID
NOMBRE
1 METANO
2 HIDRGENO
3 NITRGENO
4 CO2
5 N-BUTANO
6 AGUA
7 BENCENO
8 METANOL
9 ETANO
10 ETANOL

Tc(i) (K)
190.6
33.2
126.2
304.2
425.2
647.3
562.2
512.6
305.5
516.0

Pc(i) (kPa)
4600.2
1313.0
3400.0
7383.0
3796.0
22090.0
4898.0
8097.0
4480.0
6380.0

w(i)
0.007
-0.216
0.038
0.224
0.200
0.348
0.210
0.564
0.100
0.100

a(i)
1.702
3.249
3.280
5.457
1.935
3.470
-0.206
2.211
1.131
3.518

b(i)
9.081E-03
4.220E-04
5.930E-04
1.045E-03
3.692E-02
1.450E-03
3.906E-02
1.222E-02
1.923E-02
2.000E-02

LPA DE FORMACIN Y ENTROPA ABSOLUTA A 298 k Y 1 BAR

c(i)

d(i)

-2.164E-06 0.000E+00
0.000E+00 8.300E+03
0.000E+00 4.000E+03
0.000E+00 -1.157E+05
-1.140E-05 0.000E+00
0.000E+00 1.210E+04
-1.330E-05 0.000E+00
-3.450E-06 0.000E+00
-5.561E-06 0.000E+00
-6.002E-06 0.000E+00

hf298
-74850.0
0.0
0.0
-393520.0
-126150.0
-241820.0
82930.0
-200670.0
-84680.0
-235310.0

s298
186.16
130.68
191.61
213.80
310.12
188.83
269.20
239.70
229.49
282.59

ECUA
R=
8.314
DATOS DE LOS COMPONENTES:
Tc(i) (K)
ID
NOMBRE
1
METANO
190.6
2
HIDRGENO
33.2
3
NITRGENO
126.2
4
5
6
7
8
9
10

T (K) =
Pc(i) (kPa)

400.00
w(i)

P (kPa) =
y(i)

4600.2
1313.0
3400.0

0.007
-0.216
0.038

0.250
0.250
0.400

CO2

304.2

7383.0

0.224

0.100

N-BUTANO
AGUA
BENCENO
METANOL
ETANO
ETANOL

425.2
647.3
562.2
512.6
305.5
516.0

3796.0
22090.0
4898.0
8097.0
4480.0
6380.0

0.250

0.250

0.200
0.348
0.210
0.564
0.100
0.100
Sumay =
0.400

0.000
0.000
0.000
0.000
0.000
0.000
1.000
0.100

RK
2.17E-06

SRK
1.74E-06

y=

VALOR DEL DISCRIMINANTE (D) =

RESULTAD
RK
SRK
Peng-R
Z=
1.0002
1.0017
0.9990
PROPIEDADES RESIDUALES:
hR =
-36.922
-38.307
-51.973
R
s =
-0.094
-0.109
-0.121
vR =
0.001
0.006
-0.003
PROPIEDADES DEL GAS IDEAL REFERIDAS A 298 K Y 100 kPa (1 BAR): SIST NO REACTIVOS
(hGI - h0) =
3.317E+03
kJ/kmol
(sGI - s0) =
1.136E+00
kJ/kmol-K
vGI =
3.326
m3/kmol
PROPIEDADES ABSOLUTAS REFERIDAS A 298 K Y 100 kPa (1 BAR): SIST REACTIVOS
h0 = [yk*hf298] =
-5.806E+04
kJ/kmol
s0 = [yk*s298] =
1.772E+02
kJ/kmol-K
PROPIEDADES TERMODINMICAS DE MEZCLAS
(h - h0) =
3.280E+03
3.279E+03
3.265E+03
(s - s0) =
1.043E+00
1.027E+00
1.016E+00
( - 0) = (h - h0) - T0(s - s0)
2.969E+03
2.972E+03
2.962E+03
v=
3.326
3.331
3.322

VALORES DE Z:

ECUACIN DE ESTADO CBICAS

ESPECIFICACIONES DE LA MEZCLA:
1000.00
T0 (K) =
298.0
a(i)

b(i)

c(i)

P0 (kPa) =
d(i)

100.0

1.702
3.249
3.280

9.081E-03
4.220E-04
5.930E-04

-2.164E-06
0.000E+00
0.000E+00

0.000E+00
8.300E+03
4.000E+03

ln(p(i))
0.9163
0.9163
1.3863

5.457

1.045E-03

0.000E+00

-1.157E+05

0.0000

1.935
3.470
-0.206
2.211
1.131
3.518
1
0.000

3.692E-02
1.450E-03
3.906E-02
1.222E-02
1.923E-02
2.000E-02

-1.140E-05
0.000E+00
-1.330E-05
-3.450E-06
-5.561E-06
-6.002E-06

0.000E+00
1.210E+04
0.000E+00
0.000E+00
0.000E+00
0.000E+00

0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

0.000

0.000

0.000

0.000

Peng-R
-3.49E-08
RESULTADOS

kJ/kmol
kJ/kmol-K
m3/kmol
): SIST NO REACTIVOS

): SIST REACTIVOS

kJ/kmol
kJ/kmol-K
kJ/kmol
m3/kmol

SI EL DISCRIMINANTE ES MAYOR QUE CERO HAY UNA RAIZ REAL Y UNA FAS
SI EL DISCRIMINANTE ES MENOR QUE CERO HAY TRES RAICES REALES Y FA

NOMBRE
METANO
HIDRGENO
NITRGENO
CO2
N-BUTANO
AGUA
BENCENO
METANOL
ETANO
ETANOL

y(i)
0.250
0.250
0.400
0.100
0.000
0.000
0.000
0.000
0.000
0.000

Ecuac RK
(i)
0.9956
1.0087
1.0011
0.9870
0.9696
0.9703
0.9552
0.9675
0.9843
0.9641

FASE (1 : VAPOR; 2 : LIQ) =

hf298
-74850
0
0
-393520
-126150
-241820
82930
-200670
-84680
-235310

s298
186.16
130.68
191.61
213.80 Constantes de Cpm/R =
+ bmT + cmT2 + dmT-2
310.12
188.83
269.20
239.70
229.49
282.59

am
bm
cm
dm
[yk*ln(pk)]

=
=
=
=
=

am

3.095
2.717E-03
-5.410E-07
-7.895E+03
1.013

0.000

CERO HAY UNA RAIZ REAL Y UNA FASE HOMOGNEA

CERO HAY TRES RAICES REALES Y FASES EN EQUILIBRIO

Ecuac RK
fugacidad(i)
248.91
252.17
400.43
98.70
0.00
0.00
0.00
0.00
0.00
0.00

Ecuac SRK
fugacidad(i)
(i)
0.9975
249.37
1.0066
251.66
1.0041
401.63
0.9900
99.00
0.9740
0.00
0.9703
0.00
0.9592
0.00
0.9676
0.00
0.9877
0.00
0.9683
0.00

Ecuac Peng-R
fugacidad(i)
(i)
0.9939
248.49
1.0048
251.21
1.0016
400.64
0.9859
98.59
0.9634
0.00
0.9649
0.00
0.9470
0.00
0.9594
0.00
0.9813
0.00
0.9591
0.00

CoefA =

0.42748

CoefB =

0.08664

R=

8.314

ac = (1/Tr)
DATOS DE LOS COMPONENTES:
2

NOMBRE
METANO
HIDRGENO
NITRGENO
CO2
N-BUTANO
AGUA
BENCENO
METANOL
ETANO
ETANOL
y=
Clculos:

Tc(i) (K)
190.6
33.2
126.2
304.2
425.2
647.3
562.2
512.6
305.5
516.0

Pc(i) (kPa)
4600.2
1313.0
3400.0
7383.0
3796.0
22090.0
4898.0
8097.0
4480.0
6380.0

0.250
a=
A=

w(i)

ECUA
ESPECIFICACIONES DE L

T (K) =
FASE 1: VAPOR; 2: LIQ) =
Tr(i)
2.0986
12.0518
3.1696
1.3149
0.9407
0.6180
0.7115
0.7803
1.3093
0.7752

0.250

0.0
-0.2
0.0
0.2
0.2
0.3
0.2
0.6
0.1
0.1
Sumay =
0.400

y(i)
0.250
0.250
0.400
0.100
0.000
0.000
0.000
0.000
0.000
0.000
1.000
0.100

83.9988
0.0076

b=
B=

0.0257
0.0077

P1 =
Q1 =
R1 =

0.000

DISCRIMINANTE MAYOR QUE CERO (UNA RAIZ REAL, UNA FASE HOMOGNEA):
X1 =
0.33788
Z=
1.000
X2 =
0.32904
DISCRIMINANTE MENOR QUE CERO (TRES RAICES REALES, FASES EN EQUILIBRIO):
THETA =
0
Z(1) =
1.0002
Zmax =
1.0002
Z(2) =
-0.0001
Zmin =
-0.0001
Z(3) =
-0.0001
VALOR DE LA RAIZ DE Z:
COEFICIENTE DE
Z=
1.0002
Componente
METANO
PROPIEDADES RESIDUALES:
HIDRGENO
hR =

-36.922 kJ/kmol

s =

-0.094 kJ/kmol-K

v =
v = ZRT/P =

0.001 m3/kmol
3.326 m3/kmol

R
R

NITRGENO
CO2
N-BUTANO
AGUA
BENCENO

hR = RT*[Z-1-A/B*(1-T/a*da/dT)*ln(1 + B/Z)]

METANOL

s = R*[ln(Z-B)+A/B*(T/a*da/dT*ln(1 + B/Z)]

ETANO
ETANOL

ECUACIN DE REDLICH-KWONG (RK)

CIFICACIONES DE LA MEZCLA:

400.00
1: VAPOR; 2: LIQ) =

P (kPa) =
1

1000

ac(i)
0.6903
0.2881
0.5617
0.8721
1.0310
1.2721
1.1855
1.1320
0.8739
1.1358

alfa(i)
233.3507
24.7905
138.4126
370.3577
1407.3307
560.4687
1906.7719
958.8903
615.5740
1233.1462

a(i)
161.0796
7.1410
77.7455
322.9766
1450.9845
712.9747
2260.5503
1085.4960
537.9673
1400.5848

b(i)
0.0298
0.0182
0.0267
0.0297
0.0807
0.0211
0.0827
0.0456
0.0491
0.0583

0.000

0.000

0.000

0.000

0.000

-1.00000
-0.00019
-0.00006

M=
N=
D=

-3.335E-01
-7.419E-02
2.174E-06

phi =
Z=

1.0008
1.0002

COEFICIENTE DE FUGACIDAD Y FUGACIDAD

cphi
y(i)
fug(i) (kPa)
0.9956
0.250
248.910
1.0087
0.250
252.167
1.0011

0.400

400.433

0.9870

0.100

98.695

0.9696
0.9703
0.9552

0.000
0.000
0.000

0.000
0.000
0.000

0.9675

0.000

0.000

0.9843
0.9641

0.000
0.000

0.000
0.000

T/a*da/dT =

a(i)0,5
12.6917
2.6723
8.8173
17.9715
38.0918
26.7016
47.5452
32.9469
23.1941
37.4244

-0.50000

AP(i)
2.770
0.583
1.924
3.922
8.312
5.827
10.375
7.190
5.061
8.167

BP(i)
1.1624
0.7092
1.0413
1.1559
3.1424
0.8221
3.2201
1.7760
1.9131
2.2690

cphi(i)
0.9956
1.0087
1.0011
0.9870
0.9696
0.9703
0.9552
0.9675
0.9843
0.9641

CoefA =

0.42748

CoefB =

0.08664

R=

8.314

Tc(i) (K)
190.6
33.2
126.2
304.2
425.2
647.3
562.2
512.6
305.5
516.0

Pc(i) (kPa)
4600.2
1313.0
3400.0
7383.0
3796.0
22090.0
4898.0
8097.0
4480.0
6380.0
0.250

y(i)
0.250
0.250
0.400
0.100
0.000
0.000
0.000
0.000
0.000
0.000
1.000
0.100

Tr(i)
2.0986
12.0518
3.1696
1.3149
0.9407
0.6180
0.7115
0.7803
1.3093
0.7752

0.250

w(i)
0.007
-0.216
0.038
0.224
0.200
0.348
0.210
0.564
0.100
0.100
Sumay =
0.400

a=
A=

67.7592
0.0061

b=
B=

0.0257
7.7207E-03

P1 =
Q1 =
R1 =

fw = 0,48 + 1,57w - 0,176w

DATOS DE LOS COMPONENTES:
2

NOMBRE
METANO
HIDRGENO
NITRGENO
CO2
N-BUTANO
AGUA
BENCENO
METANOL
ETANO
ETANOL
y=
Clculos:

ECUACIN DE SO
ESPECIFICACIONES DE L

T (K) =
FASE 1: VAPOR; 2: LIQ) =

0.000

DISCRIMINANTE MAYOR QUE CERO (UNA RAIZ REAL, UNA FASE HOMOGNEA):
X1 =
0.33812
Z=
1.002
X2 =
0.33025

DISCRIMINANTE MENOR QUE CERO (TRES RAICES REALES, FASES EN EQUILIBRIO):

THETA =
0
Z(1) =
1.0017
Zmax =
1.0017
Z(2) =
-0.0008
Zmin =
-0.0008
Z(3) =
-0.0008
VALOR DE LA RAIZ DE Z:
COEFICIENTE DE
Z=
1.0017
Componente
METANO
PROPIEDADES RESIDUALES:
HIDRGENO
hR =

-38.307 kJ/kmol

NITRGENO

sR =

-0.109 kJ/kmol-K

CO2

v =
v = ZRT/P =

0.006 m3/kmol
3.3312 m3/kmol

N-BUTANO
AGUA
BENCENO

hR = RT*[Z-1-A/B*(1-T/a*da/dT)*ln(1 + B/Z)]

METANOL

s = R*[ln(Z-B)+A/B*(T/a*da/dT*ln(1 + B/Z)]

ETANO
ETANOL

ECUACIN DE SOAVE-REDLICH-KWONG (SRK)

CIFICACIONES DE LA MEZCLA:
400

P (kPa) =
1

1000

fw(i)
0.4910
0.1327
0.5394
0.8228
0.7870
1.0050
0.8019
1.3095
0.6352
0.6352

ac(i)
0.6080
0.4517
0.3353
0.7731
1.0479
1.4762
1.2668
1.3288
0.8251
1.1577

alfa(i)
233.3507
24.7905
138.4126
370.3577
1407.3307
560.4687
1906.7719
958.8903
615.5740
1233.1462

a(i)
141.8661
11.1983
46.4153
286.3403
1474.7601
827.3511
2415.4216
1274.1639
507.9220
1427.5541

b(i)
0.0298
0.0182
0.0267
0.0297
0.0807
0.0211
0.0827
0.0456
0.0491
0.0583

0.000

0.000

0.000

0.000

0.000

-1.00000
-0.00165
-0.00005

M=
N=
D=

-3.350E-01
-7.467E-02
1.740E-06

phi =
Z=

1.0006
1.0017

1: VAPOR; 2: LIQ) =

COEFICIENTE DE FUGACIDAD Y FUGACIDAD

cphi
y(i)
fug(i) (kPa)
0.9975
0.250
249.37
1.0066
0.250
251.66
1.0041

0.400

401.63

0.9900

0.100

99.00

0.9740
0.9703
0.9592

0.000
0.000
0.000

0.00
0.00
0.00

0.9676

0.000

0.00

0.9877
0.9683

0.000
0.000

0.00
0.00

T/a*da/dT =

a(i)0,5
11.9108
3.3464
6.8129
16.9216
38.4026
28.7637
49.1469
35.6954
22.5371
37.7830

-1.16924

fw(i)*(alfa(i)*Tr(i))^0,5

10.865
2.293
11.298
18.159
28.634
18.704
29.538
35.820
18.034
19.640

AP(i)
2.8939
0.8131
1.6553
4.1114
9.3305
6.9886
11.9410
8.6728
5.4758
9.1800

BP(i)
1.1624
0.7092
1.0413
1.1559
3.1424
0.8221
3.2201
1.7760
1.9131
2.2690

cphi(i)
0.9975
1.0066
1.0041
0.9900
0.9740
0.9703
0.9592
0.9676
0.9877
0.9683

F(Psat)

CoefA =

0.45724

CoefB =

fw = 0,37464 + 1,54226w - 0,26992w

DATOS DE LOS COMPONENTES:
NOMBRE
METANO
HIDRGENO
NITRGENO
CO2
N-BUTANO
AGUA
BENCENO
METANOL
ETANO
ETANOL
y=
Clculos:

ECUACIN DE
ESPECIFICACIONES DE L

0.0778

T (K) =
FASE 1: VAPOR; 2: LIQ) =

Tc(i) (K)
190.6
33.2
126.2
304.2
425.2
647.3
562.2
512.6
305.5
516.0

Pc(i) (kPa)
4600.2
1313.0
3400.0
7383.0
3796.0
22090.0
4898.0
8097.0
4480.0
6380.0

y(i)
0.250
0.250
0.400
0.100
0.000
0.000
0.000
0.000
0.000
0.000
1.000
0.100

Tr(i)
2.0986
12.0518
3.1696
1.3149
0.9407
0.6180
0.7115
0.7803
1.3093
0.7752

0.250

w(i)
0.007
-0.216
0.038
0.224
0.200
0.348
0.210
0.564
0.100
0.100
Sumay =
0.400

0.250
a=
A=

89.6637
0.008107

b=
B=

0.0231
0.00693

P1 =
Q1 =
R1 =

0.000

DISCRIMINANTE MAYOR QUE CERO (UNA RAIZ REAL, UNA FASE HOMOGNEA):
X1 =
0.00000
Z=
0.3310
X2 =
0.00000
DISCRIMINANTE MENOR QUE CERO (TRES RAICES REALES, FASES EN EQUILIBRIO):
THETA = 0.005016205
Z(1) =
0.9990
Zmax =
0.9990
Z(2) =
-0.0039
Zmin =
-0.0039
Z(3) =
-0.0020
VALOR DE LA RAIZ DE Z
Z=
0.9990
PROPIEDADES RESIDUALES:
hR =

-51.973 kJ/kmol

sR =

-0.121 kJ/kmol-K

v =
v = ZRT/P =

-0.003 m3/kmol
3.322 m3/kmol

hR = RT*{Z-1-A/(2,82843B)*(1-T/a*da/dT)*ln[(Z + 2,4142B)/(Z - 0,4142B)]}

sR = R*{ln(Z-B)+A/(2,82843B)*(T/a*da/dT)*ln[(Z + 2,4142B)/(Z - 0,4142B)]}

ECUACIN DE PENG-ROBINSON (PengR)

CIFICACIONES DE LA MEZCLA:
R=

8.314

400

P (kPa) =
1

1000

fw(i)
0.3854
0.0289
0.4329
0.7066
0.6723
0.8787
0.6866
1.1586
0.5262
0.5262

ac(i)
0.6841
0.8622
0.4385
0.8034
1.0409
1.4112
1.2265
1.2885
0.8540
1.1298

alfa(i)
249.5960
26.5164
148.0485
396.1410
1505.3052
599.4870
2039.5162
1025.6456
658.4286
1318.9945

a(i)
170.7363
22.8614
64.9264
318.2741
1566.8150
846.0053
2501.3795
1321.5738
562.2669
1490.1502

b(i)
0.0268
0.0164
0.0240
0.0267
0.0725
0.0190
0.0742
0.0409
0.0441
0.0523

0.000

0.000

0.000

0.000

0.000

-0.99307
-0.00590
-0.00001

M=
N=
D=

-3.346E-01
-7.451E-02
-3.492E-08

Z=

1.0000
0.9990

1: VAPOR; 2: LIQ) =

phi =

T/a*da/dT =

COEFICIENTE DE FUGACIDAD Y FUGACIDAD

Componente
cphi
y(i)
fug(i) (kPa)
METANO
0.9939
0.250
248.49
HIDRGENO
1.0048
0.250
251.21
NITRGENO

1.0016

0.400

400.64

CO2

0.9859

0.100

98.59

N-BUTANO
AGUA
BENCENO

0.9634
0.9649
0.9470

0.000
0.000
0.000

0.00
0.00
0.00

METANOL

0.9594

0.000

0.00

ETANO
ETANOL

0.9813
0.9591

0.000
0.000

0.00
0.00

a(i)0,5
13.0666
4.7814
8.0577
17.8402
39.5830
29.0862
50.0138
36.3535
23.7122
38.6025

-0.81294

fw(i)*(alfa(i)*Tr(i))^0,5

8.821
0.517
9.377
16.126
25.299
16.912
26.155
32.778
15.449
16.825

AP(i)
2.7598
1.0099
1.7019
3.7681
8.3605
6.1434
10.5636
7.6783
5.0083
8.1534

BP(i)
1.1624
0.7092
1.0413
1.1559
3.1424
0.8221
3.2201
1.7760
1.9131
2.2690

cphi(i)
0.9939
1.0048
1.0016
0.9859
0.9634
0.9649
0.9470
0.9594
0.9813
0.9591