Katharine Burr Blodgett

Katharine Burr Blodgett
Blodgett demonstrating equipment in lab, 1938
Born	(1898-01-10)January 10, 1898 Schenectady, New York, U.S.
Died	October 12, 1979(1979-10-12) (aged 81) Schenectady, New York, U.S.
Education	Bryn Mawr College (BA in Physics, 1917) University of Chicago (MS, 1918) Newnham College, Cambridge University (PhD in Physics, 1926)
Occupations	Physicist inventor chemist
Employer	General Electric
Known for	Surface chemistry Anti-reflective coating Langmuir–Blodgett film Langmuir–Blodgett trough
Relatives	Katharine Blodgett Gebbie (niece)
Awards	Garvan–Olin Medal (1951)

Katharine Burr Blodgett (January 10, 1898 – October 12, 1979) was an American physicist and chemist known for her work on surface chemistry, in particular her invention of "invisible" or nonreflective glass while working at General Electric. She was the first woman to be awarded a PhD in physics from the University of Cambridge, in 1926.

Early life

Blodgett was born on January 10, 1898, in Schenectady, New York. She was the second child of Katharine Buchanan (Burr) and George Reddington Blodgett. Her father was a patent attorney at General Electric where he headed that department. He was shot and killed in his home by a burglar just before she was born. GE offered a $5,000 reward for the arrest and conviction of the killer, but the suspected killer hanged himself in his jail cell in Salem, New York. Her mother was financially secure after her husband's death, and she moved to New York City with Katharine and her son George Jr. shortly after Katharine's birth.

In 1901, Katharine's mother moved the family to France so that the children would be bilingual. They lived there for several years, returned to New York for a year, during which time Katharine attended school in Saranac Lake, then spent time traveling through Germany. In 1912, Blodgett returned to New York City with her family and attended New York City's Rayson School.

Education

Blodgett's early childhood was split between New York and Europe, and she wasn't enrolled in school until she was eight years old. After attending Rayson School in New York City, she entered Bryn Mawr College on a scholarship, where she was inspired by two professors in particular: mathematician Charlotte Angas Scott and physicist James Barnes.

In 1917, Irving Langmuir, a former colleague of her father and future Nobel laureate, took Katharine on a tour of General Electric (GE)'s research laboratories. He offered her a research position at GE if she first completed higher education, so she enrolled in a master's degree program at the University of Chicago after receiving her bachelor's degree.

At the University of Chicago she studied gas adsorption with Harvey B. Lemon, researching the chemical structure of charcoals used in gas masks. She graduated in 1918 and took a research scientist position working with Langmuir. After six years at the company, Blodgett decided to pursue a doctoral degree with hopes of advancing further within GE. Langmuir arranged for her to study physics at the Cavendish Laboratory of Cambridge University, persuading somewhat reluctant administrators to offer one of their few positions to a woman. She was enrolled at Newnham College, matriculating in 1924. She studied with Sir Ernest Rutherford and in 1926 became the first woman to receive a PhD in physics from Cambridge University.

Work at General Electric

Blodgett was hired by the General Electric company as a research scientist in 1918 after receiving a master's degree from the University of Chicago. She was the first woman to work as a scientist for General Electric Laboratory in Schenectady, NY. She often worked with Irving Langmuir, who had pioneered a technique for creating single-molecule thin films on the surface of water. Blodgett and Langmuir explored the application of similar techniques to lipids, polymers, and proteins, creating monomolecular coatings designed to cover surfaces of water, metal, or glass. These special coatings were oily and could be deposited in layers only a few nanometers thick.

In 1935, Blodgett extended Langmuir's work by devising a method to spread multiple layers of a monomolecular coating, one layer at a time, onto glass or metal. By repeatedly dipping a metal plate into water covered by a layer of a long-chain fatty acid, she was able to stack layers onto the plate with molecular precision. The apparatus which she used and refined is known as the Langmuir–Blodgett trough.

Blodgett used barium stearate to cover glass with 44 monomolecular layers, making the glass more than 99% transmissive and creating "invisible" glass. The visible light reflected by the layers of film canceled the reflections created by the glass. This type of coating is referred to as nonreflective or antireflective because very little light is reflected.

While in principle, Blodgett's multilayer thin films had potential for use as antireflective coatings, General Electric never commercialized the films because they were too fragile and could easily be wiped off a surface. Other types of films which employed antireflective inorganic compounds proved more useful commercially.

Blodgett also invented a color gauge, a method to measure the thickness of molecular coatings on glass to the nearest one millionth of an inch. The gauge employed the concept that different thicknesses of coatings are different colors. While examining the layering of stearic acid on a glass plate, she realized that the addition of each layer, about 2/10,000,000 inch thick, reliably changed the color of the plate. Before her invention, the best measurement instruments were only accurate to a few thousandths of an inch. Her glass "ruler" much more precisely showed the progression of colors and their corresponding thicknesses. Measuring thickness became as simple as matching colors. The color gauge was marketed for a time by General Electric.

Blodgett and Langmuir also worked on improvements to the light bulb. Their studies on electrical discharges in gases helped lay the foundations for plasma physics.

Blodgett was issued eight U.S. patents during her career. She was the sole inventor on all but two of the patents, working with Vincent J. Schaefer as co-inventor. Blodgett published over 30 technical papers in various scientific journals. Her research also included the investigation of methods for deicing aircraft wings, and improving smokescreens during WWII.

Personal life

Blodgett bought a home in Schenectady overlooking her birthplace where she spent most of her adult life. Blodgett was an active community member and indulged in various hobbies. She was known for her contributions to civic affairs, including roles in the Travelers Aid Society and the General Electric employee's club. Her interests spanned gardening, astronomy, antiquing, and playing bridge with friends. She was an actress in her town's theater group and volunteered for civic and charitable organizations. She had a sharp wit and was known for writing an occasional funny poem.

Blodgett spent time during the summer at a camp at Lake George in upstate New York, where other General Electric scientists also owned property, and she pursued her love of gardening. Even after retiring in 1963, Blodgett continued her horticultural experiments, demonstrating her lifelong commitment to exploration and discovery. She died in her home on October 12, 1979, leaving behind a legacy of innovation, resilience, and breaking barriers for women in science and engineering.

Blodgett's niece and namesake was astrophysicist and civil servant Katharine Blodgett Gebbie. In an interview, Gebbie recalled that on family visits her Aunt Katie:

"always arrived with suitcases full of 'apparatus', with which she showed us such wonders as how to make colors by dipping glass rods into thin films of oil floating on water."

Gebbie often spoke in later life of her aunt's influence by personal example on her choice of a career in science.

Awards

Blodgett received numerous awards during her lifetime. She received a star in the seventh edition of American Men of Science (1943), recognizing her as one of the 1,000 most distinguished scientists in the United States. In 1945, the American Association of University Women honored her with its Annual Achievement Award.

In 1951 she received the prestigious Francis Garvan Medal from the American Chemical Society for her work on thin films. That same year, she was chosen by the U.S. Chamber of Commerce as one of 15 "women of achievement." Also in 1951, she was honored in Boston's First Assembly of American Women in Achievement (the only scientist in the group), and the mayor of Schenectady honored her with Katharine Blodgett Day on June 13, 1951, because of all the honor she had brought to her community.

In 1972, the Photographic Society of America presented her with its Annual Achievement Award and in 2007 she was inducted into the National Inventors Hall of Fame. In 2008, an elementary school in Schenectady bearing her name was opened.

She received honorary doctorates from Elmira College (1939), Western College (1942), Brown University (1942), and Russell Sage College (1944).

Blodgett's accomplishments were widely recognized, earning her several prestigious awards. In 1945, she received the Achievement Award from the American Association of University Women, and in 1951, she was honored with the Garvan-Olin Medal by the American Chemical Society. These accolades were a testament to her groundbreaking work as a scientist and her role as a trailblazer for women in the field.

Patents

• U.S. patent 2,220,860 issued November 5, 1940: "Film Structure and Method of Preparation"
• U.S. patent 2,220,861 issued November 5, 1940: "Reduction of Surface Reflection"
• U.S. patent 2,220,862 issued November 5, 1940: "Low-Reflectance Glass"
• U.S. patent 2,493,745 issued January 10, 1950: "Electrical Indicator of Mechanical Expansion" (with Vincent J. Schaefer)
• U.S. patent 2,587,282 issued February 26, 1952: "Step Gauge for Measuring Thickness of Thin Films"
• U.S. patent 2,589,983 issued March 18, 1952: "Electrical Indicator of Mechanical Expansion" (with Vincent J. Schaefer)
• U.S. patent 2,597,562 issued May 20, 1952: "Electrically Conducting Layer"
• U.S. patent 2,636,832 issued April 28, 1953: "Method of Forming Semiconducting Layers on Glass and Article Formed Thereby"

See also

• Notable American Women by the Radcliffe Institute, Harvard University

Further reading

• Shearer, Benjamin F.; Shearer, Barbara Smith (1997). Notable women in the physical sciences: a biographical dictionary (ebook ed.). Westport, Conn.: Greenwood Press. ISBN 9780313293030. OCLC 644247606.
• Byers, Nina; Williams, Gary A. (2006). Out of the shadows : contributions of twentieth-century women to physics (Print book, English ed.). Cambridge, UK; New York: Cambridge University Press. ISBN 978-0521821971. OCLC 62891583.
• Making contributions : an historical overview of women's role in physics (Print book: Biography: English ed.). College Park, MD: American Association of Physics Teachers. 1984. ISBN 978-0917853098. OCLC 12196220.