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$\beta$-NMR of copper isotopes in ionic liquids / Stachura, Monika (TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, Canada V6T 2A3)
CERN-INTC-2020-016 ; INTC-SR-105. - 2020.
Fulltext - Original Document (INTC-P-393)

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Direct Observation of Nanosecond Water Exchange Dynamics at a Protein Metal Site / Stachura, Monika (Copenhagen U.) ; Chakraborty, Saumen (Michigan State U., Dept. Chem.) ; Gottberg, Alexander (CERN) ; Ruckthong, Leela (Michigan State U., Dept. Chem.) ; Pecoraro, Vincent L (Michigan State U., Dept. Chem.) ; Hemmingsen, Lars (Copenhagen U.)
Nanosecond ligand exchange dynamics at metal sites within proteins is essential in catalysis, metal ion transport, and regulatory metallobiochemistry. Herein we present direct observation of the exchange dynamics of water at a $Cd^{2+}$ binding site within two de novo designed metalloprotein constructs using $^{111m}$Cd perturbed angular correlation (PAC) of γ-rays and $^{113}$Cd NMR spectroscopy. [...]
2017 - 4 p. - Published in : J. Am. Chem. Soc. 139 (2017) 79-82

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TDPAC and β-NMR applications in chemistry and biochemistry / Jancso, Attila (Szeged U.) ; Correia, Joao G (CERN ; IST/ITN, Lisbon) ; Gottberg, Alexander (TRIUMF) ; Schell, Juliana (CERN ; Duisburg-Essen U.) ; Stachura, Monika (TRIUMF) ; Szunyogh, D (Szeged U. ; Copenhagen U.) ; Pallada, Stavroula (CERN ; Bohr Inst. ; Democritus U., Thrace) ; Lupascu, Doru C (Duisburg-Essen U.) ; Kowalska, Magdalena (CERN) ; Hemmingsen, Lars (Bohr Inst.)
Time differential perturbed angular correlation (TDPAC) of γ-rays spectroscopy has been applied in chemistry and biochemistry for decades. Herein we aim to present a comprehensive review of chemical and biochemical applications of TDPAC spectroscopy conducted at ISOLDE over the past 15 years, including elucidation of metal site structure and dynamics in proteins and model systems. [...]
2017 - 25 p. - Published in : J. Phys. G 44 (2017) 064003

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Specificity of the Metalloregulator CueR for Monovalent Metal Ions: Possible Functional Role of a Coordinated Thiol? / Szunyogh, Dániel (MTA‐SZTE Bioinorganic Chemistry Research Group, Hungary) ; Szokolai, Hajnalka (Szeged U.) ; Thulstrup, Peter W (Copenhagen U.) ; Larsen, Flemming H (Copenhagen U.) ; Gyurcsik, Béla (Szeged U.) ; Christensen, Niels Johan (Copenhagen U.) ; Stachura, Monika (CERN ; TRIUMF) ; Hemmingsen, Lars (Copenhagen U.) ; Jancsó, Attila (Szeged U.)
Metal-ion-responsive transcriptional regulators within the MerR family effectively discriminate between mono- and divalent metal ions.Herein we address the origin of the specificity of the CueR protein for monovalent metal ions.Several spectroscopic techniques were employed to study $Ag^I$ ,$Zn^{II}$ ,and $Hg^{II}$ binding to model systems encompassing the metal-ion-binding loop of CueR from E. coli and V. [...]
2015 - 6 p. - Published in : Angew. Chem. Int. Ed. 54 (2015) 15756-15761

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Study of the kinetics of complex formation and in vivo stability of novel radiometal-chelate conjugates for applications in nuclear medicine / Radchenko, Valery (TRIUMF, Canada) ; Stachura, Monika (TRIUMF, Canada) ; Ramogida, Caterina (TRIUMF, Canada) ; Hoehr, Cornelia (TRIUMF, Canada) ; Schaffer, Paul (TRIUMF, Canada) ; Orvig, Chris (University of British Columbia, Canada) ; Filosofov, Dmitry (Joint Institute for Nuclear Research (JINR), Russian Federation) ; Kurakina, Elena (oint Institute for Nuclear Research (JINR), Russian Federation) ; Hemmingsen, Lars (University of Copenhagen, Denmark) ; Thurstrup, Peter W (University of Copenhagen, Denmark) et al.
CERN-INTC-2017-019 ; INTC-P-501. - 2017.
Fulltext

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Billion-Fold Enhancement in Sensitivity of Nuclear Magnetic Resonance Spectroscopy for Magnesium Ions in Solution / COLLAPS collaboration
β-nuclear magnetic resonance (NMR) spectroscopy is highly sensitive compared to conventional NMR spectroscopy, and may be applied for several elements across the periodic table. β-NMR has previously been successfully applied in the fields of nuclear and solid-state physics. [...]
2014 - Published in : Chem. Phys. Chem. 15 (2014) 3929-3932

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VITO setup: Status Report / Stachura, Monika (CERN) ; Johnston, Karl (Saarland U.) ; Gottberg, Alexander (CERN) ; Bissell, Mark L (IKS Leuven, Belgium) ; Garcia Ruiz, Ronald F (IKS Leuven, Belgium) ; Martins Correia, Joao (Lisbon U.) ; Granadeiro Costa, Angelo R (Aveiro U.) ; Dehn, Martin (Munich, Tech. U.) ; Deicher, Manfred (Saarland U.) ; Fenta, Abel (Aveiro U.) et al.
CERN-INTC-2015-015 ; INTC-SR-050. - 2015.
Fulltext

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CERN-MEDICIS (MEDical Isotopes Collected from ISOLDE): A new facility / Augusto, Ricardo Manuel dos Santos (CERN) ; Buehler, Leo (HUG, Geneva) ; Lawson, Zoe (CERN) ; Marzari, Stefano (CERN) ; Stachura, Monika (CERN) ; Stora, Thierry (CERN) /CERN-MEDICIS Collaboration
About 50% of the 1.4GeV CERN’s protons are sent onto targets to produce radioactive beams by online mass separation at ISOLDE, for a wide range of studies in fundamental and applied physics. CERN-MEDICIS is a spin-off dedicated to R&D; in life sciences and medical applications. [...]
CERN-ACC-NOTE-2014-0019.- Geneva : CERN, 2014 - 13 p. - Published in : Appl. Sci. 4 (2014) 265-281 Fulltext: PDF; MDPI Open Access article: PDF;

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Nuclear techniques using radioactive beams for biophysical studies / Stachura, Monika Kinga
Perturbed angular correlation of "-rays (PAC) spectroscopy and nuclear magnetic resonance measured by !-decay (betaNMR) spectroscopy are two very sensitive and, among life-scientists, infrequently encountered nuclear techniques [...]
CERN-THESIS-2012-402. - 96 p.

DART-Europe E-theses Portal server - CERN Isolde server - Cover page - Coppenhagen U. server

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β-NMR of copper isotopes in ionic liquids / Stachura, Monika (CERN) ; Hemmingsen, Lars (Department of Chemistry, University of Copenhagen, Denmark) ; Gottberg, Alexander (CERN) ; Kowalska, Magdalena (CERN) ; Bissell, Mark L (Institute for Nuclear and Radiation Physics, KU Leuven, Belgium) ; Bjerrum, Morten J (Department of Chemistry, University of Copenhagen, Denmark) ; Flanagan, Kieran (School of Physics and Astronomy, University of Manchester, United Kingdom) ; Garcia Ruiz, Ronald F (Institute for Nuclear and Radiation Physics, KU Leuven, Belgium) ; Georgiev, Georgi (CSNSM, Orsay, France) ; Jancso, Attila (Department of Chemistry, University of Szeged, Hungary) et al.
CERN-INTC-2013-034 ; INTC-P-393. - 2013.
Fulltext

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