Author(s)
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Correia, J G (CERN) ; Capponi, J J (Laboratoire de Cristallographie, CNRS) ; Ctortecka, B (Univ. Leipzig) ; Butz, T (Univ Leipzig) ; Tröger, W (Univ. Leipzig) ; Araújo, J P (IFIMUP, Departamento de Física) ; Loureiro, S M (Princeton Univ.) ; Toulemonde, P (Laboratoire de Cristallographie, CNRS) ; Gatt, R (Univ. of Illinois) ; Le Floc'h, S (Laboratoire de Cristallographie, CNRS) ; Bordet, P (Laboratoire de Cristallographie, CNRS) |
Abstract
| Electric-field gradients on mercury sites of the HgBa$_{2}$CuO$_{4+\delta}$ high-$T_{C}$ superconductor were measured with the perturbed angular correlation technique and interpreted with $\textit{ab initio}$ calculations. Under oxygen annealing, an asymmetric electric-field gradient has been assigned to the presence of single oxygen atoms, O$_{\delta}$ , which are located in the Hg planes. These experiments provide an atomic scale tool for studying charge-density variations occuring in the neighborhood of the Hg atoms, which can be induced, particularly, by pointlike defects. |