CERN Accelerating science

Article
Title Cu-Ti Formation in Nb-Ti/Cu Superconducting Strand Monitored by in situ Techniques
Author(s) Pong, I (CERN) ; Oberli, Luc-Rene (CERN) ; Pong, Ian (CERN) ; Gerardin, Alexandre (CERN) ; Scheuerlein, Christian (CERN) ; Bottura, Luca (CERN)
Publication 2010
In: Defect and Diffusion Forum 297-301 (2010) 695-701
In: 5th International Conference on Diffusion in Solids and Liquids, Rome, Italy, 24 - 26 Jun 2009, pp.695-701
DOI 10.4028/www.scientific.net/DDF.297-301.695
Subject category Engineering
Abstract In order to investigate the high temperature exposure effect on Nb-Ti/Cu superconducting strands, as might be encountered in joining by soldering and in cabling annealing, X-ray diffraction and resistometry measurements were performed in situ during heat treatment, and complemented by conventional metallography, mechanical tests and superconducting properties measurements. Changes of the Nb-Ti nanostructure at temperatures above 300 degrees C are manifested in the degradation of critical current in an applied external magnetic field, although degradation at self field was insignificant up to 400 degrees C for several minutes. Above 500 degrees C, the formation of various Cu-Ti intermetallic compounds, due to Ti diffusion from Nb-Ti into Cu, is detected by in situ XRD albeit not resolvable by SEM-EDS. There is a ductile to brittle transition near 600 degrees C, and liquid formation is observed below 900 degrees C. The formation of Cu-Ti causes a delayed reduction of the residual resistivity ratio (RRR) and adversely affects the deformation behaviour of the strands.

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