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1.
New particle formation from isoprene under upper-tropospheric conditions / Shen, Jiali (Helsinki U.) ; Russell, Douglas M (Frankfurt U., FIAS) ; DeVivo, Jenna (Carnegie Mellon U.) ; Kunkler, Felix (Mainz, Max Planck Inst.) ; Baalbaki, Rima (Helsinki U.) ; Mentler, Bernhard (Innsbruck U.) ; Scholz, Wiebke (Innsbruck U.) ; Yu, Wenjuan (Helsinki U.) ; Caudillo-Plath, Lucía (Frankfurt U., FIAS) ; Sommer, Eva (CERN ; Vienna U.) et al.
Abstract Aircraft observations have revealed ubiquitous new particle formation in the tropical upper troposphere over the Amazon1,2 and the Atlantic and Pacific oceans3,4. Although the vapours involved remain unknown, recent satellite observations have revealed surprisingly high night-time isoprene mixing ratios of up to 1 part per billion by volume (ppbv) in the tropical upper troposphere5. [...]
2024 - 9 p. - Published in : Nature 636 (2024) 115-123 Fulltext: PDF; External link: Interactions.org
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2.
Iodine oxoacids enhance nucleation of sulfuric acid particles in the atmosphere / He, Xu-Cheng (Helsinki U. ; Carnegie Mellon U. ; Helsinki Inst. of Phys.) ; Simon, Mario (Frankfurt U., FIAS ; Frankfurt U.) ; Iyer, Siddharth (Tampere U. of Tech.) ; Xie, Hong-Bin (Shanghai Jiao Tong U.) ; Rörup, Birte (Helsinki U.) ; Shen, Jiali (Helsinki U.) ; Finkenzeller, Henning (Colorado U. ; Colorado U., CIRES) ; Stolzenburg, Dominik (Helsinki U. ; Vienna U.) ; Zhang, Rongjie (Shanghai Jiao Tong U.) ; Baccarini, Andrea (PSI, Villigen ; Ecole Polytechnique, Lausanne) et al.
The main nucleating vapor in the atmosphere is thought to be sulfuric acid (H2SO4), stabilized by ammonia (NH3). However, in marine and polar regions, NH3 is generally low, and H2SO4 is frequently found together with iodine oxoacids [HIOx, i.e., iodic acid (HIO3) and iodous acid (HIO2)]. [...]
2023 - 7 p. - Published in : Science 382 (2023) adh2526 Manuscript: PDF;
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3.
The gas-phase formation mechanism of iodic acid as an atmospheric aerosol source / Finkenzeller, Henning (Colorado U. ; Colorado U., CIRES) ; Iyer, Siddharth (Tampere U. of Tech.) ; He, Xu-Cheng (Helsinki U.) ; Simon, Mario (Goethe U., Frankfurt (main)) ; Koenig, Theodore K (Colorado U. ; Colorado U., CIRES ; Peking U., Beijing) ; Lee, Christopher F (Colorado U. ; Colorado U., CIRES) ; Valiev, Rashid (Helsinki U.) ; Hofbauer, Victoria (Carnegie Mellon U.) ; Amorim, Antonio (Lisbon U.) ; Baalbaki, Rima (Helsinki U.) et al.
AbstractIodine is a reactive trace element in atmospheric chemistry that destroys ozone and nucleates particles. Iodine emissions have tripled since 1950 and are projected to keep increasing with rising O3 surface concentrations. [...]
2022 - 7 p. - Published in : Nature Chem. 15 (2022) 129-135 Fulltext: PDF;
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4.
High Gas-Phase Methanesulfonic Acid Production in the OH-Initiated Oxidation of Dimethyl Sulfide at Low Temperatures / Shen, Jiali ; Scholz, Wiebke ; He, Xu-Cheng ; Zhou, Putian ; Marie, Guillaume ; Wang, Mingyi ; Marten, Ruby ; Surdu, Mihnea ; Rörup, Birte ; Baalbaki, Rima et al.
Dimethyl sulfide (DMS) influences climate via cloud condensation nuclei (CCN) formation resulting from its oxidation products (mainly methanesulfonic acid, MSA, and sulfuric acid, H2SO4). Despite their importance, accurate prediction of MSA and H2SO4 from DMS oxidation remains challenging. [...]
2022 - 14 p. - Published in : Environ. Sci. Technol. 56 (2022) 13931-13944 Fulltext: PDF;
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5.
Critical Role of Iodous Acid in Neutral Iodine Oxoacid Nucleation / Zhang, Rongjie ; Xie, Hong-Bin ; Ma, Fangfang ; Chen, Jingwen ; Iyer, Siddharth ; Simon, Mario ; Heinritzi, Martin ; Shen, Jiali ; Tham, Yee Jun ; Kurtén, Theo et al.
Nucleation of neutral iodine particles has recently been found to involve both iodic acid (HIO3) and iodous acid (HIO2). However, the precise role of HIO2 in iodine oxoacid nucleation remains unclear. [...]
2022 - 12 p. - Published in : Environ. Sci. Technol. 56 (2022) 14166-14177 Fulltext: PDF;
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6.
Determination of the collision rate coefficient between charged iodic acid clusters and iodic acid using the appearance time method / He, Xu-Cheng (U. Helsinki (main)) ; Iyer, Siddharth (U. Helsinki (main)) ; Sipilä, Mikko (U. Helsinki (main)) ; Ylisirniö, Arttu (UEF, Kuopio) ; Peltola, Maija (Helsinki U.) ; Kontkanen, Jenni (Helsinki U.) ; Baalbaki, Rima (Helsinki U.) ; Simon, Mario (Goethe U., Frankfurt (main)) ; Kürten, Andreas (Goethe U., Frankfurt (main)) ; Tham, Yee Jun (Helsinki U.) et al.
Ions enhance the formation rate of atmospheric aerosol particles, which play an important role in Earth’s radiative balance. Ion-induced nucleation involves the stepwise accretion of neutral monomers onto a molecular cluster containing an ion, which helps to stabilize the cluster against evaporation. [...]
2020 - 12 p. - Published in : Aerosol Sci. Technol. 55 (2020) 231-242 Fulltext: PDF;
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7.
Measurement of iodine species and sulfuric acid using bromide chemical ionization mass spectrometers / Wang, Mingyi (Carnegie Mellon U.) ; He, Xu-Cheng (Helsinki U.) ; Finkenzeller, Henning (U. Colorado, Boulder) ; Iyer, Siddharth (Helsinki U.) ; Chen, Dexian (Carnegie Mellon U.) ; Shen, Jiali (Helsinki U.) ; Simon, Mario (Frankfurt U.) ; Hofbauer, Victoria (Carnegie Mellon U.) ; Kirkby, Jasper (CERN ; Frankfurt U.) ; Curtius, Joachim (Frankfurt U.) et al.
Iodine species are important in the marine atmosphere for oxidation and new-particle formation. Understanding iodine chemistry and iodine new-particle formation requires high time resolution, high sensitivity, and simultaneous measurements of many iodine species. [...]
2021 - 16 p. - Published in : Atmos. Meas. Tech. 14 (2021) 4187-4202 Fulltext: PDF; Supplement: PDF;
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8.
Role of iodine oxoacids in atmospheric aerosol nucleation / He, Xu-Cheng (Helsinki U.) ; Tham, Yee Jun (Helsinki U.) ; Dada, Lubna (Helsinki U.) ; Wang, Mingyi (Carnegie Mellon U.) ; Finkenzeller, Henning (U. Colorado, Boulder) ; Stolzenburg, Dominik (Vienna U. ; Helsinki U.) ; Iyer, Siddharth (Tampere U. of Tech.) ; Simon, Mario (Frankfurt U., FIAS) ; Kürten, Andreas (Frankfurt U., FIAS) ; Shen, Jiali (Helsinki U.) et al.
Iodic acid (HIO3) is known to form aerosol particles in coastal marine regions, but predicted nucleation and growth rates are lacking. Using the CERN CLOUD (Cosmics Leaving Outdoor Droplets) chamber, we find that the nucleation rates of HIO3 particles are rapid, even exceeding sulfuric acid–ammonia rates under similar conditions. [...]
2021 - 7 p. - Published in : Science 371 (2021) 589-595
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Veja também: nomes de autores similares
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3 Iyer, S K
3 Iyer, S P
2 Iyer, S R
1 Iyer, S S
4 Iyer, S V
1 Iyer, Sai
1 Iyer, Savitri V
1 Iyer, Shrivats Mohan
3 Iyer, Srikanth K
1 Iyer, Subbu
1 Iyer, Swami
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