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1.
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Potential pre-industrial–like new particle formation induced by pure biogenic organic vapors in Finnish peatland
/ Huang, Wei (Helsinki U.) ; Junninen, Heikki (Tartu, Inst. Phys.) ; Garmash, Olga (Tampere U. of Tech. ; Washington U., Seattle) ; Lehtipalo, Katrianne (Helsinki U.) ; Stolzenburg, Dominik (TU Vienna) ; Lampilahti, Janne L P (Helsinki U.) ; Ezhova, Ekaterina (Helsinki U.) ; Schallhart, Simon (STUK, Helsinki) ; Rantala, Pekka (Helsinki U.) ; Aliaga, Diego (Helsinki U.) et al.
Pure biogenic new particle formation (NPF) induced by highly oxygenated organic molecules (HOMs) could be an important mechanism for pre-industrial aerosol formation. However, it has not been unambiguously confirmed in the ambient due to the scarcity of truly pristine continental locations in the present-day atmosphere or the lack of chemical characterization of NPF precursors. [...]
2024 - 11 p.
- Published in : Sci. Adv. 10 (2024) adm9191
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2.
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Role of sesquiterpenes in biogenic new particle formation
/ Dada, Lubna (PSI, Villigen ; Helsinki U.) ; Stolzenburg, Dominik (Helsinki U. ; Vienna U. ; TU Vienna) ; Simon, Mario (Frankfurt U.) ; Fischer, Lukas (Innsbruck U.) ; Heinritzi, Martin (Frankfurt U.) ; Wang, Mingyi (Carnegie Mellon U. ; Caltech) ; Xiao, Mao (PSI, Villigen) ; Vogel, Alexander L (Frankfurt U.) ; Ahonen, Lauri (Helsinki U.) ; Amorim, Antonio (Lisbon U.) et al.
Biogenic vapors form new particles in the atmosphere, affecting global climate. The contributions of monoterpenes and isoprene to new particle formation (NPF) have been extensively studied. [...]
2023 - 14 p.
- Published in : Sci. Adv. 9 (2023) adi5297
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3.
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NO at low concentration can enhance the formation of highly oxygenated biogenic molecules in the atmosphere
/ Nie, Wei (Nanjing U. (main) ; Unlisted, CN ; Helsinki U. ; SYRTE, Paris) ; Yan, Chao (Nanjing U. (main) ; Unlisted, CN ; Helsinki U. ; SYRTE, Paris) ; Yang, Liwen (Nanjing U. (main)) ; Roldin, Pontus (Khlopin Radium Inst. ; Malmo U.) ; Liu, Yuliang (Nanjing U. (main)) ; Vogel, Alexander L (Frankfurt U., FIAS ; Frankfurt U.) ; Molteni, Ugo (PSI, Villigen ; UC, Irvine (main) ; Unlisted, US) ; Stolzenburg, Dominik (Helsinki U. ; Vienna U.) ; Finkenzeller, Henning (Colorado U.) ; Amorim, Antonio (CMAF, Lisbon) et al.
The interaction between nitrogen monoxide (NO) and organic peroxy radicals (RO$_{2}$) greatly impacts the formation of highly oxygenated organic molecules (HOM), the key precursors of secondary organic aerosols. It has been thought that HOM production can be significantly suppressed by NO even at low concentrations. [...]
2023 - 11 p.
- Published in : Nature Commun. 14 (2023) 3347
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4.
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High Gas-Phase Methanesulfonic Acid Production in the OH-Initiated Oxidation of Dimethyl Sulfide at Low Temperatures
/ Shen, Jiali ; Scholz, Wiebke ; He, Xu-Cheng ; Zhou, Putian ; Marie, Guillaume ; Wang, Mingyi ; Marten, Ruby ; Surdu, Mihnea ; Rörup, Birte ; Baalbaki, Rima et al.
Dimethyl sulfide (DMS) influences climate via cloud condensation nuclei (CCN) formation resulting from its oxidation products (mainly
methanesulfonic acid, MSA, and sulfuric acid, H2SO4). Despite their importance,
accurate prediction of MSA and H2SO4 from DMS oxidation remains
challenging. [...]
2022 - 14 p.
- Published in : Environ. Sci. Technol. 56 (2022) 13931-13944
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5.
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Determination of the collision rate coefficient between charged iodic acid clusters and iodic acid using the appearance time method
/ He, Xu-Cheng (U. Helsinki (main)) ; Iyer, Siddharth (U. Helsinki (main)) ; Sipilä, Mikko (U. Helsinki (main)) ; Ylisirniö, Arttu (UEF, Kuopio) ; Peltola, Maija (Helsinki U.) ; Kontkanen, Jenni (Helsinki U.) ; Baalbaki, Rima (Helsinki U.) ; Simon, Mario (Goethe U., Frankfurt (main)) ; Kürten, Andreas (Goethe U., Frankfurt (main)) ; Tham, Yee Jun (Helsinki U.) et al.
Ions enhance the formation rate of atmospheric aerosol particles, which play an important role in Earth’s radiative balance. Ion-induced nucleation involves the stepwise accretion of neutral monomers onto a molecular cluster containing an ion, which helps to stabilize the cluster against evaporation. [...]
2020 - 12 p.
- Published in : Aerosol Sci. Technol. 55 (2020) 231-242
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6.
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The driving factors of new particle formation and growth in the polluted boundary layer
/ Xiao, Mao ; Hoyle, Christopher R ; Dada, Lubna ; Stolzenburg, Dominik ; Kürten, Andreas ; Wang, Mingyi ; Lamkaddam, Houssni ; Garmash, Olga ; Mentler, Bernhard ; Molteni, Ugo et al.
New particle formation (NPF) is a significant
source of atmospheric particles, affecting climate and air
quality. Understanding the mechanisms involved in urban
aerosols is important to develop effective mitigation strategies. [...]
2021 - 17 p.
- Published in : Atmos. Chem. Phys. 21 (2021) 14275-14291
Fulltext: PDF; Supplement: PDF;
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7.
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Formation of Highly Oxygenated Organic Molecules from $\alpha$-Pinene Ozonolysis: Chemical Characteristics, Mechanism, and Kinetic Model Development
/ Molteni, Ugo (PSI, Villigen) ; Simon, Mario (Frankfurt U.) ; Heinritzi, Martin (Frankfurt U.) ; Hoyle, Christopher R (PSI, Villigen) ; Bernhammer, Anne-Kathrin (Ionicon GesmbH, Innsbruck) ; Bianchi, Federico (Helsinki U.) ; Breitenlechner, Martin (Innsbruck U.) ; Brilke, Sophia (Frankfurt U.) ; Dias, António (Lisbon U.) ; Duplissy, Jonathan (Helsinki U. ; Helsinki Inst. of Phys.) et al.
Terpenes are emitted by vegetation, and their oxidation in the
atmosphere is an important source of secondary organic aerosol (SOA). A part of
this oxidation can proceed through an autoxidation process, yielding highly
oxygenated organic molecules (HOMs) with low saturation vapor pressure. [...]
2019 - 11 p.
- Published in : ACS Earth and Space Chemistry 3 (2019) 873-883
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8.
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Molecular understanding of new-particle formation from $\alpha$-pinene between −50 and +25 °C
/ Simon, Mario (Frankfurt U.) ; Dada, Lubna (Helsinki U.) ; Heinritzi, Martin (Frankfurt U.) ; Scholz, Wiebke (Innsbruck U.) ; Stolzenburg, Dominik (Vienna U.) ; Fischer, Lukas (Innsbruck U.) ; Wagner, Andrea C (Frankfurt U. ; U. Colorado, Boulder) ; Kürten, Andreas (Frankfurt U.) ; Rörup, Birte (Helsinki U.) ; He, Xu-Cheng (Helsinki U.) et al.
Highly oxygenated organic molecules (HOMs)
contribute substantially to the formation and growth of atmospheric aerosol particles, which affect air quality, human
health and Earth’s climate. HOMs are formed by rapid, gasphase autoxidation of volatile organic compounds (VOCs)
such as α-pinene, the most abundant monoterpene in the atmosphere. [...]
2020 - 25 p.
- Published in : Atmos. Chem. Phys. 20 (2020) 9183-9207
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9.
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Molecular understanding of the suppression of new-particle formation by isoprene
/ Heinritzi, Martin (Frankfurt U.) ; Dada, Lubna (Helsinki U.) ; Simon, Mario (Frankfurt U.) ; Stolzenburg, Dominik (Vienna U.) ; Wagner, Andrea C (Frankfurt U. ; U. Colorado, Boulder) ; Fischer, Lukas (Innsbruck U.) ; Ahonen, Lauri R (Helsinki U.) ; Amanatidis, Stavros (Caltech, Pasadena (main)) ; Baalbaki, Rima (Helsinki U.) ; Baccarini, Andrea (PSI, Villigen) et al.
Nucleation of atmospheric vapours produces more
than half of global cloud condensation nuclei and so has
an important influence on climate. Recent studies show
that monoterpene (C$_{10}$H$_{16}$) oxidation yields highly oxygenated products that can nucleate with or without sulfuric acid. [...]
2020 - 13 p.
- Published in : Atmos. Chem. Phys. 20 (2020) 11809-11821
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10.
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Role of iodine oxoacids in atmospheric aerosol nucleation
/ He, Xu-Cheng (Helsinki U.) ; Tham, Yee Jun (Helsinki U.) ; Dada, Lubna (Helsinki U.) ; Wang, Mingyi (Carnegie Mellon U.) ; Finkenzeller, Henning (U. Colorado, Boulder) ; Stolzenburg, Dominik (Vienna U. ; Helsinki U.) ; Iyer, Siddharth (Tampere U. of Tech.) ; Simon, Mario (Frankfurt U., FIAS) ; Kürten, Andreas (Frankfurt U., FIAS) ; Shen, Jiali (Helsinki U.) et al.
Iodic acid (HIO3) is known to form aerosol particles in coastal marine regions, but predicted nucleation and growth rates are lacking. Using the CERN CLOUD (Cosmics Leaving Outdoor Droplets) chamber, we find that the nucleation rates of HIO3 particles are rapid, even exceeding sulfuric acid–ammonia rates under similar conditions. [...]
2021 - 7 p.
- Published in : Science 371 (2021) 589-595
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