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Verfasst von:Thauer, Elisa [VerfasserIn]   i
 Zakharova, G. S. [VerfasserIn]   i
 Andreikov, E. I. [VerfasserIn]   i
 Adam, Viktor [VerfasserIn]   i
 Wegener, Simon [VerfasserIn]   i
 Nölke, Jan-Hinrich [VerfasserIn]   i
 Singer, Lennart [VerfasserIn]   i
 Ottmann, Alexander [VerfasserIn]   i
 Asyuda, A. [VerfasserIn]   i
 Zharnikov, Michael [VerfasserIn]   i
 Kiselkov, D. M. [VerfasserIn]   i
 Zhu, Q. [VerfasserIn]   i
 Puzyrev, I. S. [VerfasserIn]   i
 Podval’naya, N. V. [VerfasserIn]   i
 Klingeler, Rüdiger [VerfasserIn]   i
Titel:Novel synthesis and electrochemical investigations of ZnO/C composites for lithium-ion batteries
Verf.angabe:E. Thauer, G.S. Zakharova, E. I. Andreikov, V. Adam, S.A. Wegener, J. -H. Nölke, L. Singer, A. Ottmann, A. Asyuda, M. Zharnikov, D.M. Kiselkov, Q. Zhu, I.S. Puzyrev, N.V. Podval’naya, and R. Klingeler
E-Jahr:2021
Jahr:12 May 2021
Umfang:16 S.
Fussnoten:Gesehen am 27.07.2022
Titel Quelle:Enthalten in: Journal of materials science
Ort Quelle:Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966
Jahr Quelle:2021
Band/Heft Quelle:56(2021), 23, Seite 13227-13242
ISSN Quelle:1573-4803
Abstract:For the first time, ZnO/C composites were synthesized using zinc glycerolate as a precursor through one-step calcination under a nitrogen atmosphere. The effect of the heat treatment conditions on the structure, composition, morphology as well as on the electrochemical properties regarding application in lithium-ion batteries are investigated. The products obtained by calcination of the precursor in nitrogen at 400—800 °C consist of zinc oxide nanoparticles and amorphous carbon that is in-situ generated from organic components of the glycerolate precursor. When used as anode material for lithium-ion batteries, the as-prepared ZnO/C composite synthesized at a calcination temperature of 700 °C delivers initial discharge and charge capacities of 1061 and 671 mAh g−1 at a current rate of 100 mA g−1 and hence 1.5 times more than bare ZnO, which reaches only 749/439 mAh g−1. The native carbon improves the conductivity, allowing efficient electronic conductivity and Li-ion diffusion. By means of ex-situ XRD studies a two-step storage mechanism is proven.
DOI:doi:10.1007/s10853-021-06125-4
URL:kostenfrei: Volltext: https://doi.org/10.1007/s10853-021-06125-4
 DOI: https://doi.org/10.1007/s10853-021-06125-4
Datenträger:Online-Ressource
Sprache:eng
K10plus-PPN:181071382X
Verknüpfungen:→ Zeitschrift
 
 
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