| |  Online-Ressource |
|---|
| Verfasst von: | Ott, Jonas C. [VerfasserIn]  |
|---|
| | Wadepohl, Hubert [VerfasserIn] |
|---|
| | Gade, Lutz H. [VerfasserIn] |
|---|
| Titel: | Opening up the valence shell |
|---|
| Titelzusatz: | a T-shaped iron(I) metalloradical and its potential for atom abstraction |
|---|
| Verf.angabe: | Jonas C. Ott, Hubert Wadepohl, and Lutz H. Gade |
|---|
| Jahr: | 2020 |
|---|
| Umfang: | 5 S. |
|---|
| Fussnoten: | First published: 20 March 2020 ; Gesehen am 16.11.2021 |
|---|
| Titel Quelle: | Enthalten in: Angewandte Chemie / International edition |
|---|
| Ort Quelle: | Weinheim : Wiley-VCH, 1962 |
|---|
| Jahr Quelle: | 2020 |
|---|
| Band/Heft Quelle: | 59(2020), 24, Seite 9448-9452 |
|---|
| ISSN Quelle: | 1521-3773 |
|---|
| Abstract: | A thermally stable, T-shaped, d7 high-spin iron(I) complex was obtained by reduction of a PNP-supported ferrous chloride. Paramagnetic NMR spectroscopy combined with DFT modeling was used to analyze the electronic structure of the coordinatively highly unsaturated complex. The metalloradical character of the compound was demonstrated by the formation of a benzophenone ketyl radical complex upon addition of benzophenone. Furthermore, the compound displays a rich chemistry as an oxygen-atom abstractor from epoxides, yielding a dinuclear, diferrous [Fe2O] complex. |
|---|
| DOI: | doi:10.1002/anie.202003118 |
|---|
| URL: | kostenfrei: Volltext ; Verlag: https://doi.org/10.1002/anie.202003118 |
|---|
| | kostenfrei: Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202003118 |
|---|
| | DOI: https://doi.org/10.1002/anie.202003118 |
|---|
| Datenträger: | Online-Ressource |
|---|
| Sprache: | eng |
|---|
| Bibliogr. Hinweis: | Parallele Sprachausgabe : deutschOtt, Jonas C., 1991 - : Öffnung der Valenzschale |
|---|
| Sach-SW: | iron |
|---|
| | ketyl complexes |
|---|
| | oxido complexes |
|---|
| | paramagnetic NMR spectroscopy |
|---|
| | T-shaped complexes |
|---|
| K10plus-PPN: | 1777541719 |
|---|
| Verknüpfungen: | → Zeitschrift |
|---|
| |
|
|---|
| | |
|---|
| Lokale URL UB: |  Zum Volltext |
|---|
Opening up the valence shell / Ott, Jonas C. [VerfasserIn]; 2020 (Online-Ressource)
Andere Auflagen/Ausgaben:
Zurück zur Trefferübersicht und Suche
