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Status: 
| Verfasst von: | Qiu, Kangwen |
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| | Han, Yuning |
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| | Guo, Wenbo |
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| | Wang, Licun |
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| | Cheng, Jinbing |
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| | Luo, Yongsong |
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| Titel: | Synthesis of highly twinned ZnSe nanorods for enhancing N2 electrochemical conversion to NH3 |
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| Verlagsort: | Cambridge |
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| Verlag: | Royal Society of Chemistry |
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| Jahr: | 2023 |
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| Fussnoten: | ObjectType-Article-1 ; ObjectType-Feature-2 ; SourceType-Scholarly Journals-1 ; content type line 23 |
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| Inhalt: | In this work, we report an atomistic understanding of the hydrogenation behavior of a highly twinned ZnSe nanorod (T-ZnSe) with a large density of surface atomic steps and the activation of N2 molecules adsorbed on its surface. Theoretical calculations suggest that the atomic steps are essential for the hydrogenation of T-ZnSe, which greatly enhances its catalytic activity. As a result, the T-ZnSe nanorods exhibit a significantly enhanced NH3 production rate of 13.3 μg h−1 mg−1 and faradaic efficiency of 5.83% towards the NRR compared with the pristine ZnSe nanorods. This report offers an important pathway for the development of efficient catalysts for the NRR, and a versatile anion-exchange strategy for efficiently manipulating materials’ functionalities. |
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| ISSN: | 1359-7345 |
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| Titel Quelle: | Chemical communications (Cambridge, England) |
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| Jahr Quelle: | 2023 |
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| Band/Heft Quelle: | 59, 17, S. 2465-2468 |
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| DOI: | doi:10.1039/d2cc06776e |
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| URL: | http://www.ub.uni-heidelberg.de/cgi-bin/edok?dok=https%3A%2F%2Ffanyv88.com%3A443%2Fhttps%2Fsearch.proquest.com%2Fdocview%2F2779004578 |
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| | http://www.ub.uni-heidelberg.de/cgi-bin/edok?dok=https%3A%2F%2Ffanyv88.com%3A443%2Fhttps%2Fsearch.proquest.com%2Fdocview%2F2774497336 |
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| | DOI: https://doi.org/10.1039/d2cc06776e |
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| Sprache: | English |
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| Sach-SW: | Ammonia |
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| | Anion exchanging |
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| | Catalytic activity |
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| | Hydrogenation |
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| | Nanorods |
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| Verknüpfungen: | → Sammelwerk |
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