Zinc aluminium
Zinc-aluminium (ZA) alloys are alloys whose main constituents are zinc and aluminium.Zn has a solubility of around 1.14 %wt. at 381 °C and about 0.7 %wt. at 277 °C.[1] Other alloying elements include magnesium and copper. This type of alloy was originally developed for gravity casting. Noranda, New Jersey Zinc Co. Ltd., St. Joe Mineral Co. and the International Lead Zinc Research Organization (ILZRO) were the main companies that pioneered the ZA alloys between the 1950s and the 1970s. They were designed to compete with bronze, cast iron and aluminium using sand and permanent mold casting methods. Distinguishing features of ZA alloys include high as-cast strength, excellent bearing properties, as well as low energy requirements (for melting).[2]
ZA alloys make good bearings because their final composition includes hard eutectic zinc-aluminium-copper particles embedded in a softer zinc-aluminium matrix. The hard particles provide a low-friction bearing surface, while the softer material wears back to provide space for lubricant to flow, similar to Babbitt metal.[citation needed]
The numbers associated with the name represent the amount of aluminium in the alloy (i.e. ZA8 has 8% aluminium).[2]
| ZA8 | ZA12 | ZA27 | ||||
|---|---|---|---|---|---|---|
| Mechanical properties | Sand cast | Permanent mold | Sand cast | Permanent mold | Sand cast | Permanent mold |
| Ultimate tensile strength [ksi (MPa)] | 38 (263) | 32-37 (221-255) | 40-46 (276-317) | 45-50 (310-345) | 58-64 (400-441) | 45-47 (310-324) |
| Yield strength - 0.2% offset [ksi (MPa)] | 29 (200) | 30 (206) | 31 (214) | 39 (269) | 54 (372) | 37 (255) |
| Elongation [% in 2"] | 1-2 | 1-2 | 1-3 | 1-3 | 3-6 | 8-11 |
| Shear strength [ksi (MPa)] | - | 35 (241) | 37 (255) | - | 42 (290) | 33 (228) |
| Hardness [Brinell] | 85 | 85-90 | 89-105 | 89-105 | 110-120 | 90-110 |
| Impact strength [ft·lbf (J)] | 156 (20) | - | 193 (25) | - | 353 (47) | 433 (58) |
| Fatigue strength rotary bend in 5x108 cycles [ksi (MPa)] | - | 7.5 (52) | 15 (103) | - | 25 (172) | 15 (103) |
| Compressive yield strength 0.1% offset [ksi (MPa)] | 29 (199) | 31 (214) | 33 (227) | 34 (234) | 48 (331) | 37 (255) |
| Modulus of elasticity [psi x 106 (GPa)] | 12.4 (85.5) | 12.47 (85.5) | 12.07 (82.7) | 12.07 (82.7) | 11.37 (77.9) | 11.37 (77.9) |
| Poisson's ratio | 0.29 | 0.29 | 0.30 | 0.30 | 0.32 | 0.32 |
| Physical properties | Sand cast | Permanent mold | Sand cast | Permanent mold | Sand cast | Permanent mold |
| Density [lb/in3 (g/cm3)] | .227 (6.3) | 0.227 (6.3) | 0.218 (6.0) | 0.218 (6.0) | 0.181 (5.0) | 0.181 (5.0) |
| Melting Range | 375-404°C (707-759°F) | 375-404°C (707-759°F) | 377-432°C (710-810°F) | 377-432°C (710-810°F) | 376-484°C (708-903°F) | 376-484°C (708-903°F) |
| Electrical Conductivity [S/m (%IACS)] | 1.61 (27.7) | 1.61 (27.7) | 1.64 (28.3) | 1.64 (28.3) | 1.72 (29.7) | 1.72 (29.7) |
| Thermal Conductivity [BTU/hr/ft2/°R (W/m/K)] | 66.3 (114.7) | 66.3 (114.7) | 67.1 (116.1) | 67.1 (116.1) | 72.5 (125.5) | 72.5 (125.5) |
| CTE [68-212°F μin/in/°R (100-200°C μm/m/K)] | 12.9 (23.3) | 12.9 (23.3) | 13.4 (24.2) | 13.4 (24.2) | 14.4 (26.0) | 14.4 (26.0) |
| Specific Heat [BTU/lb/°R (J/kg/K)] | .104 (435) | .104 (435) | .107 (448) | .107 (448) | .125 (523) | .125 (523) |
| Pattern of Die Shrinkage [in/ft (mm/m)] | 1/8 (10.4) | 1/8 (10.4) | 5/32 (13.0) | 5/32 (13.0) | 5/32 (13.0) | 5/32 (13.0) |
| ZA8 | ZA12 | ZA27 | ||||
|---|---|---|---|---|---|---|
| Composition | Ingot | Casting | Ingot | Casting | Ingot | Casting |
| Al | 8.2-8.8 | 8.0-8.8 | 10.8-11.5 | 10.5-11.5 | 25.5-28.0 | 25.0-28.0 |
| Mg | .020-.030 | .015-.030 | .020-.030 | .015-.030 | .012-.020 | .010-.020 |
| Cu | 0.8-1.3 | 0.8-1.3 | 0.5-1.2 | 0.5-1.2 | 2.0-2.5 | 2.0-2.5 |
| Fe (max) | .065 | .075 | .065 | .075 | .072 | .075 |
| Pb (max) | .005 | .006 | .005 | .006 | .005 | .006 |
| Cd | .005 | .006 | .005 | .006 | .005 | .006 |
| Sn (max) | .002 | .003 | .002 | .003 | .002 | .003 |
| Ni (other)x10 | - | - | - | - | - | - |
| Zn | Bal | Bal | Bal | Bal | Bal | Bal |
| Color Code ASTM B908 | Blue | Blue | Orange | Orange | Purple | Purple |
See also
References
- ^ Kong L, Heydari Z, Lami GH, Saberi A, Baltatu MS, Vizureanu P. A comprehensive review of the current research status of biodegradable zinc alloys and composites for biomedical applications. Materials. 2023 Jul 3;16(13):4797.https://www.mdpi.com/1996-1944/16/13/4797
- ^ a b c d "Gravity Casting Alloys". Eastern Alloys, Inc. Retrieved 2007-07-19.