Cyclopropenone: Difference between revisions
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| IUPACName = 2-Cyclopropen-1-one |
| IUPACName = 2-Cyclopropen-1-one |
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| OtherNames = Cyclopropenone, Cyclopropene-3-one |
| OtherNames = Cyclopropenone, Cyclopropene-3-one |
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| Section2 = {{Chembox Properties |
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| C=3|H=2|O=1 |
| C=3|H=2|O=1 |
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| Appearance = colorless |
| Appearance = colorless gas |
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| Density = |
| Density = |
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| MeltingPt = −29 to −28 °C |
| MeltingPt = −29 to −28 °C |
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'''Cyclopropenone''' is an [[organic compound]] with [[molecular formula]] C<sub>3</sub>H<sub>2</sub>O consisting of a [[cyclopropene]] carbon framework with a [[ketone]] [[functional group]]. It is a colorless gas.<ref>R. Breslow, J. Pecoraro, T. Sugimoto "Cyclpropenone" Org. Synth. 1977, vol. 57, pp. 41. {{DOI|10.15227/orgsyn.057.0041}}</ref> The chemical properties of the compound are dominated by the strong [[dielectric|polarization]] of the [[carbonyl]] group, which a partial positive charge on the ring and a partial negative charge on oxygen. Other cyclic unsaturated ketones, e.g., [[tropone]], [[cyclopentadienone]], also exhibit unusual properties. |
'''Cyclopropenone''' is an [[organic compound]] with [[molecular formula]] C<sub>3</sub>H<sub>2</sub>O consisting of a [[cyclopropene]] carbon framework with a [[ketone]] [[functional group]]. It is a colorless gas.<ref>R. Breslow, J. Pecoraro, T. Sugimoto "Cyclpropenone" Org. Synth. 1977, vol. 57, pp. 41. {{DOI|10.15227/orgsyn.057.0041}}</ref> The chemical properties of the compound are dominated by the strong [[dielectric|polarization]] of the [[carbonyl]] group, which a partial positive charge on the ring and a partial negative charge on oxygen. Other cyclic unsaturated ketones, e.g., [[tropone]], [[cyclopentadienone]], also exhibit unusual properties. |
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[[File:C3H2OResonance.png|thumb|left|Main resonance structures of cyclopropenone.]] |
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==References== |
==References== |
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Revision as of 17:30, 23 September 2015
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| Names | |
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| IUPAC name
2-Cyclopropen-1-one
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| Other names
Cyclopropenone, Cyclopropene-3-one
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| Identifiers | |
3D model (JSmol)
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| C3H2O | |
| Molar mass | 54.048 g·mol−1 |
| Appearance | colorless gas |
| Density | |
| Melting point | −29 to −28 °C |
| Boiling point | |
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| Hazards | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Cyclopropenone is an organic compound with molecular formula C3H2O consisting of a cyclopropene carbon framework with a ketone functional group. It is a colorless gas.[1] The chemical properties of the compound are dominated by the strong polarization of the carbonyl group, which a partial positive charge on the ring and a partial negative charge on oxygen. Other cyclic unsaturated ketones, e.g., tropone, cyclopentadienone, also exhibit unusual properties.
References
- ^ R. Breslow, J. Pecoraro, T. Sugimoto "Cyclpropenone" Org. Synth. 1977, vol. 57, pp. 41. doi:10.15227/orgsyn.057.0041
