Cyclopropenone: Difference between revisions
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| C=3|H=2|O=1 |
| C=3|H=2|O=1 |
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| Appearance = colorless |
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| Density = |
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| MeltingPt = |
| MeltingPt = −29 to −28 °C |
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| BoilingPt = |
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'''Cyclopropenone''' is an [[organic compound]] with [[molecular formula]] C<sub>3</sub>H<sub>2</sub>O consisting of a [[cyclopropene]] carbon framework with a [[ketone]] [[functional group]]. |
'''Cyclopropenone''' is an [[organic compound]] with [[molecular formula]] C<sub>3</sub>H<sub>2</sub>O consisting of a [[cyclopropene]] carbon framework with a [[ketone]] [[functional group]]. It is a colorless gas.<ref>R. Breslow, J. Pecoraro, T. Sugimoto "Cyclpropenone" Org. Synth. 1977, vol. 57, pp. 41. {{DOI|10.15227/orgsyn.057.0041}}</ref> The chemical properties of the compound are dominated by the strong [[dielectric|polarization]] of the [[carbonyl]] group, which a partial positive charge on the ring and a partial negative charge on oxygen. Other cyclic unsaturated ketones, e.g., [[tropone]], [[cyclopentadienone]], also exhibit unusual properties. |
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==Properties== |
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The [[carbonyl]] group is [[dielectric|polarized]] with a partial positive charge on the carbon atom and a partial negative charge on oxygen. |
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==See also== |
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* Other cyclic ketones: [[cyclopropanone]], [[tropone]], [[cyclopentadienone]] |
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* Other cyclopropene derivatives: [[cyclopropene]], [[methylcyclopropenone]] |
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==References== |
==References== |
Revision as of 11:52, 23 September 2015
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Names | |
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IUPAC name
2-Cyclopropen-1-one
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Other names
Cyclopropenone, Cyclopropene-3-one
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Identifiers | |
3D model (JSmol)
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PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
C3H2O | |
Molar mass | 54.048 g·mol−1 |
Appearance | colorless |
Density | |
Melting point | −29 to −28 °C |
Boiling point | |
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Hazards | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Cyclopropenone is an organic compound with molecular formula C3H2O consisting of a cyclopropene carbon framework with a ketone functional group. It is a colorless gas.[1] The chemical properties of the compound are dominated by the strong polarization of the carbonyl group, which a partial positive charge on the ring and a partial negative charge on oxygen. Other cyclic unsaturated ketones, e.g., tropone, cyclopentadienone, also exhibit unusual properties.
References
- ^ R. Breslow, J. Pecoraro, T. Sugimoto "Cyclpropenone" Org. Synth. 1977, vol. 57, pp. 41. doi:10.15227/orgsyn.057.0041