Tin triphosphide: Difference between revisions
Content deleted Content added
+ |
Citation bot (talk | contribs) Altered url. URLs might have been anonymized. Add: pmc, pmid, doi-access. Removed URL that duplicated identifier. Removed access-date with no URL. | Use this bot. Report bugs. | Suggested by Headbomb | Linked from Wikipedia:WikiProject_Academic_Journals/Journals_cited_by_Wikipedia/Sandbox | #UCB_webform_linked 23/24 |
||
| Line 40: | Line 40: | ||
}} |
}} |
||
}} |
}} |
||
'''Tin triphosphide''' is a binary [[inorganic compound]] of [[tin]] metal and [[phosphorus]] with the chemical formula {{chem2|SnP3}}.<ref>{{cite book |last1=Jacobson |first1=Carl Alfred |last2=Hampel |first2=Clifford A. |title=Encyclopedia of Chemical Reactions |date=1946 |publisher=Reinhold Publishing Corporation |page=15 |url=https:// |
'''Tin triphosphide''' is a binary [[inorganic compound]] of [[tin]] metal and [[phosphorus]] with the chemical formula {{chem2|SnP3}}.<ref>{{cite book |last1=Jacobson |first1=Carl Alfred |last2=Hampel |first2=Clifford A. |title=Encyclopedia of Chemical Reactions |date=1946 |publisher=Reinhold Publishing Corporation |page=15 |url=https://books.google.com/books?id=vXYMAQAAIAAJ&q=tin+triphosphide+snp3 |access-date=28 March 2024 |language=en}}</ref> |
||
== Preparation == |
== Preparation == |
||
| Line 47: | Line 47: | ||
==Physical properties== |
==Physical properties== |
||
Tin triphosphide forms crystals of [[trigonal crystal system]], spatial group ''R3m'' with six formula units in a unit cell of dimensions a = 7.378Å and c = 10.512Å.<ref>{{cite journal |last1=Gullman |first1=Jan |last2=Olofsson |first2=Olle |title=The crystal structure of SnP3 and a note on the crystal structure of GeP3 |journal=[[Journal of Solid State Chemistry]] |date=1 November 1972 |volume=5 |issue=3 |pages=441–445 |doi=10.1016/0022-4596(72)90091-6 |url=https://www.sciencedirect.com/science/article/abs/pii/0022459672900916 |
Tin triphosphide forms crystals of [[trigonal crystal system]], spatial group ''R3m'' with six formula units in a unit cell of dimensions a = 7.378Å and c = 10.512Å.<ref>{{cite journal |last1=Gullman |first1=Jan |last2=Olofsson |first2=Olle |title=The crystal structure of SnP3 and a note on the crystal structure of GeP3 |journal=[[Journal of Solid State Chemistry]] |date=1 November 1972 |volume=5 |issue=3 |pages=441–445 |doi=10.1016/0022-4596(72)90091-6 |url=https://www.sciencedirect.com/science/article/abs/pii/0022459672900916 |access-date=28 March 2024 |issn=0022-4596}}</ref><ref>{{cite web |title=mp-7541: SnP3 (trigonal, R-3m, 166) |url=https://legacy.materialsproject.org/materials/mp-7541/ |publisher=[[Materials Project]] |access-date=28 March 2024}}</ref> |
||
Insoluble in {{chem2|H2O}} and [[HCl]]. Soluble in [[Nitric acid|{{chem2|HNO3}}]].<ref>{{cite book |last1=Sangeeta |first1=D. |title=Inorganic Materials Chemistry Desk Reference |date=25 June 1997 |publisher=[[CRC Press]] |isbn=978-0-8493-8900-9 |page=275 |url=https:// |
Insoluble in {{chem2|H2O}} and [[HCl]]. Soluble in [[Nitric acid|{{chem2|HNO3}}]].<ref>{{cite book |last1=Sangeeta |first1=D. |title=Inorganic Materials Chemistry Desk Reference |date=25 June 1997 |publisher=[[CRC Press]] |isbn=978-0-8493-8900-9 |page=275 |url=https://books.google.com/books?id=bdGXyilNsGMC&dq=tin+triphosphide+snp3&pg=RA4-PA11 |access-date=28 March 2024 |language=en}}</ref> |
||
==Uses== |
==Uses== |
||
{{chem2|SnP3}} can be used in high-performance energy storage devices.<ref>{{cite journal |last1=Yan |first1=Miaomiao |last2=Yang |first2=Bingchao |last3=Sun |first3=Xiujie |last4=Wang |first4=Zhixiu |last5=Jiang |first5=Xingang |last6=Yi |first6=Wencai |last7=Sun |first7=Hairui |last8=Yang |first8=Ruilong |last9=Ding |first9=Hao |last10=Yue |first10=Dongdong |last11=Zhai |first11=Kun |last12=Li |first12=Yueqing |last13=Chen |first13=Xin |last14=Zhang |first14=Yongsheng |last15=Liu |first15=Xiaobing |title=High-Quality 2D SnP 3 Nanosheets: Novel Flexible Electrode for Energy Storage Device Application with Wide Temperature Adaptivity |journal=ACS Materials Letters |date=1 January 2024 |volume=6 |issue=1 |pages=194–202 |doi=10.1021/acsmaterialslett.3c01438 |url=https://pubs.acs.org/doi/abs/10.1021/acsmaterialslett.3c01438 |access-date=28 March 2024 |language=en |issn=2639-4979}}</ref><ref>{{cite journal |last1=Zhang |first1=Ningxia |last2=Li |first2=Xiaodan |last3=Ruan |first3=Shihao |last4=Chen |first4=Xiong |last5=Li |first5=Shenghao |last6=Hu |first6=Taotao |title=First-Principles Study of Electronic Properties of Substitutionally Doped Monolayer SnP3 |journal=Materials |date=27 March 2022 |volume=15 |issue=7 |pages=2462 |doi=10.3390/ma15072462 | |
{{chem2|SnP3}} can be used in high-performance energy storage devices.<ref>{{cite journal |last1=Yan |first1=Miaomiao |last2=Yang |first2=Bingchao |last3=Sun |first3=Xiujie |last4=Wang |first4=Zhixiu |last5=Jiang |first5=Xingang |last6=Yi |first6=Wencai |last7=Sun |first7=Hairui |last8=Yang |first8=Ruilong |last9=Ding |first9=Hao |last10=Yue |first10=Dongdong |last11=Zhai |first11=Kun |last12=Li |first12=Yueqing |last13=Chen |first13=Xin |last14=Zhang |first14=Yongsheng |last15=Liu |first15=Xiaobing |title=High-Quality 2D SnP 3 Nanosheets: Novel Flexible Electrode for Energy Storage Device Application with Wide Temperature Adaptivity |journal=ACS Materials Letters |date=1 January 2024 |volume=6 |issue=1 |pages=194–202 |doi=10.1021/acsmaterialslett.3c01438 |url=https://pubs.acs.org/doi/abs/10.1021/acsmaterialslett.3c01438 |access-date=28 March 2024 |language=en |issn=2639-4979}}</ref><ref>{{cite journal |last1=Zhang |first1=Ningxia |last2=Li |first2=Xiaodan |last3=Ruan |first3=Shihao |last4=Chen |first4=Xiong |last5=Li |first5=Shenghao |last6=Hu |first6=Taotao |title=First-Principles Study of Electronic Properties of Substitutionally Doped Monolayer SnP3 |journal=Materials |date=27 March 2022 |volume=15 |issue=7 |pages=2462 |doi=10.3390/ma15072462 |doi-access=free |pmid=35407794 |pmc=8999696 }}</ref> |
||
==References== |
==References== |
||
Revision as of 11:12, 28 March 2024
| Identifiers | |
|---|---|
| Properties | |
| P3Sn | |
| Molar mass | 211.631 g·mol−1 |
| Appearance | crystals |
| Density | 4.05 g/cm3 |
| insoluble | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Tin triphosphide is a binary inorganic compound of tin metal and phosphorus with the chemical formula SnP3.[1]
Preparation
Tin triphosphide can be formed from the fusion of stoichiometric amounts of both elements at 580 °C:
- Sn + 3P → SnP3
Physical properties
Tin triphosphide forms crystals of trigonal crystal system, spatial group R3m with six formula units in a unit cell of dimensions a = 7.378Å and c = 10.512Å.[2][3]
Insoluble in H2O and HCl. Soluble in HNO3.[4]
Uses
SnP3 can be used in high-performance energy storage devices.[5][6]
References
- ^ Jacobson, Carl Alfred; Hampel, Clifford A. (1946). Encyclopedia of Chemical Reactions. Reinhold Publishing Corporation. p. 15. Retrieved 28 March 2024.
- ^ Gullman, Jan; Olofsson, Olle (1 November 1972). "The crystal structure of SnP3 and a note on the crystal structure of GeP3". Journal of Solid State Chemistry. 5 (3): 441–445. doi:10.1016/0022-4596(72)90091-6. ISSN 0022-4596. Retrieved 28 March 2024.
- ^ "mp-7541: SnP3 (trigonal, R-3m, 166)". Materials Project. Retrieved 28 March 2024.
- ^ Sangeeta, D. (25 June 1997). Inorganic Materials Chemistry Desk Reference. CRC Press. p. 275. ISBN 978-0-8493-8900-9. Retrieved 28 March 2024.
- ^ Yan, Miaomiao; Yang, Bingchao; Sun, Xiujie; Wang, Zhixiu; Jiang, Xingang; Yi, Wencai; Sun, Hairui; Yang, Ruilong; Ding, Hao; Yue, Dongdong; Zhai, Kun; Li, Yueqing; Chen, Xin; Zhang, Yongsheng; Liu, Xiaobing (1 January 2024). "High-Quality 2D SnP 3 Nanosheets: Novel Flexible Electrode for Energy Storage Device Application with Wide Temperature Adaptivity". ACS Materials Letters. 6 (1): 194–202. doi:10.1021/acsmaterialslett.3c01438. ISSN 2639-4979. Retrieved 28 March 2024.
- ^ Zhang, Ningxia; Li, Xiaodan; Ruan, Shihao; Chen, Xiong; Li, Shenghao; Hu, Taotao (27 March 2022). "First-Principles Study of Electronic Properties of Substitutionally Doped Monolayer SnP3". Materials. 15 (7): 2462. doi:10.3390/ma15072462. PMC 8999696. PMID 35407794.