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{{chembox
{{chembox
| Verifiedfields = changed
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 415702375
| verifiedrevid = 415702375
|ImageFile=Methidathion.png
| ImageFile=Methidathion vector.svg
|ImageSize=200px
| ImageSize=200px
| PIN=''S''-[(5-Methoxy-2-oxo-1,3,4-thiadiazol-3(2''H'')-yl)methyl] ''O'',''O''-dimethyl phosphorodithioate
|IUPACName=3-(dimethoxyphosphinothioylsulfanylmethyl)-5-methoxy-1,3,4-thiadiazol-2-one
|OtherNames= Supracide, Ultracide, Suprathion
| OtherNames= Supracide, Ultracide, Suprathion
|Section1= {{Chembox Identifiers
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 13115
| ChemSpiderID = 13115
| KEGG_Ref = {{keggcite|correct|kegg}}
| KEGG_Ref = {{keggcite|correct|kegg}}
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| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo=950-37-8
| CASNo=950-37-8
| UNII_Ref = {{fdacite|correct|FDA}}
⚫
| PubChem=13709
| UNII = Y2P145U7KK
⚫
| ChEBI_Ref = {{ebicite|changed|EBI}}
⚫
| PubChem=13709
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| ChEBI_Ref = {{ebicite|changed|EBI}}
| ChEBI = 34837
| ChEBI = 34837
| SMILES = O=C1SC(=N/N1CSP(=S)(OC)OC)\OC
| SMILES = O=C1SC(=N/N1CSP(=S)(OC)OC)\OC
}}
}}
|Section2= {{Chembox Properties
|Section2={{Chembox Properties
| Formula=C<sub>6</sub>H<sub>11</sub>N<sub>2</sub>O<sub>4</sub>PS<sub>3</sub>
| Formula=C<sub>6</sub>H<sub>11</sub>N<sub>2</sub>O<sub>4</sub>PS<sub>3</sub>
| MolarMass=302.331
| MolarMass=302.331 g/mol
| Appearance=
| Appearance=
| Density=
| Density=
| MeltingPt=
| MeltingPt=
| BoilingPt=
| BoilingPt=
| Solubility=
| Solubility=
}}
}}
|Section3= {{Chembox Hazards
|Section3={{Chembox Hazards
| MainHazards=
| MainHazards=
| FlashPt=
| FlashPt=
| AutoignitionPt =
| Autoignition=
}}
}}
}}
}}


'''Methidathion''' is an [[organophosphate]] [[insecticide]]; its use is banned in the European Community.<ref>[http://www.pan-europe.info/Resources/Links/Banned_in_the_EU.pdf]</ref>
'''Methidathion''' is an [[organophosphate]] [[insecticide]];<ref>{{cite journal|title=The effects of methidathion on liver: role of vitamins E and C|journal=Toxicology and Industrial Health|volume=19|issue=2–6|pages=63–67|doi=10.1191/0748233703th176oa|pmid=15697176|year=2016|last1=Gokalp|first1=Osman|last2=Gulle|first2=Kanat|last3=Sulak|first3=Osman|last4=Cicek|first4=Ekrem|last5=Altuntas|first5=Irfan|s2cid=23209774}}</ref> its use is banned in the European Union and USA.<ref>{{Cite web |url=http://www.pan-europe.info/Resources/Links/Banned_in_the_EU.pdf |title=Archived copy |access-date=2012-03-02 |archive-date=2013-06-05 |archive-url=https://web.archive.org/web/20130605090824/http://www.pan-europe.info/Resources/Links/Banned_in_the_EU.pdf |url-status=dead }}</ref>

Methidathion has been used as an insecticide in many countries to control caterpillars of ''[[Indarbela quadrinotata]]''.<ref>{{cite web | url=http://kiengiangbiospherereserve.com.vn/project/uploads/doc/12.Control_bark_eating_caterpillar.pdf | title=CONTROL OF BARK EATING CATERPILLAR | publisher=German Development Cooperation | access-date=13 July 2016 | url-status=dead | archive-url=https://web.archive.org/web/20160813081430/http://kiengiangbiospherereserve.com.vn/project/uploads/doc/12.Control_bark_eating_caterpillar.pdf | archive-date=13 August 2016 }}</ref>

In 2012, residues were found in Thai vegetables at levels 100 times the legal limit. [[Thailand]] routinely uses many pesticides banned in the US and EU and in amounts far exceeding limits.<ref>{{Cite web|url=http://www.nationmultimedia.com/life/The-pesticides-on-our-plates-30188702.html|title = Nation Thailand news website, thai news, thailand news, Bangkok thailand, aec, breaking news : Nation Thailand}}</ref>


==References==
==References==
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* [http://extoxnet.orst.edu/pips/methidat.htm Extoxnet]
* [http://extoxnet.orst.edu/pips/methidat.htm Extoxnet]


{{insecticides}}
{{Insecticides}}
{{Acetylcholine metabolism and transport modulators}}
{{Cholinergics}}
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{{organic-compound-stub}}


[[Category:Acetylcholinesterase inhibitors]]
[[Category:Organophosphate insecticides]]
[[Category:Organophosphate insecticides]]
[[Category:Anticholinesterases]]
[[Category:Thiadiazoles]]
[[Category:Thiadiazoles]]
[[Category:Ethers]]
[[Category:Ethers]]
[[Category:Phosphorodithioates]]
[[Category:Phosphorodithioates]]



[[ca:Metidatió]]
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{{organic-compound-stub}}
[[de:Methidathion]]

Latest revision as of 23:29, 13 July 2022

Methidathion
Names
Preferred IUPAC name
S-[(5-Methoxy-2-oxo-1,3,4-thiadiazol-3(2H)-yl)methyl] O,O-dimethyl phosphorodithioate
Other names
Supracide, Ultracide, Suprathion
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.012.227 Edit this at Wikidata
KEGG
UNII
  • InChI=1S/C6H11N2O4PS3/c1-10-5-7-8(6(9)16-5)4-15-13(14,11-2)12-3/h4H2,1-3H3 checkY
    Key: MEBQXILRKZHVCX-UHFFFAOYSA-N checkY
  • InChI=1/C6H11N2O4PS3/c1-10-5-7-8(6(9)16-5)4-15-13(14,11-2)12-3/h4H2,1-3H3
    Key: MEBQXILRKZHVCX-UHFFFAOYAL
  • O=C1SC(=N/N1CSP(=S)(OC)OC)\OC
Properties
C6H11N2O4PS3
Molar mass 302.331 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Methidathion is an organophosphate insecticide;[1] its use is banned in the European Union and USA.[2]

Methidathion has been used as an insecticide in many countries to control caterpillars of Indarbela quadrinotata.[3]

In 2012, residues were found in Thai vegetables at levels 100 times the legal limit. Thailand routinely uses many pesticides banned in the US and EU and in amounts far exceeding limits.[4]

References

[edit]
  1. ^ Gokalp, Osman; Gulle, Kanat; Sulak, Osman; Cicek, Ekrem; Altuntas, Irfan (2016). "The effects of methidathion on liver: role of vitamins E and C". Toxicology and Industrial Health. 19 (2–6): 63–67. doi:10.1191/0748233703th176oa. PMID 15697176. S2CID 23209774.
  2. ^ "Archived copy" (PDF). Archived from the original (PDF) on 2013-06-05. Retrieved 2012-03-02.{{cite web}}: CS1 maint: archived copy as title (link)
  3. ^ "CONTROL OF BARK EATING CATERPILLAR" (PDF). German Development Cooperation. Archived from the original (PDF) on 13 August 2016. Retrieved 13 July 2016.
  4. ^ "Nation Thailand news website, thai news, thailand news, Bangkok thailand, aec, breaking news : Nation Thailand".
[edit]


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