Maraging steel: Difference between revisions

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Processing of maraging steel: SLM is a brand name. The process is being called as LPBF these days.
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{{Short description|Steel known for strength and toughness}}
{{Steels}}
'''Maraging steels''' (a [[portmanteau]] of "[[martensitic]]" and "aging") are [[steel]]s that are known for possessing superior strength and toughness without losing [[ductility]]. ''Aging'' refers to the extended heat-treatment process. These steels are a special class of very-low-[[carbon]] ultra-high-strength steels that derive their strength not from carbon, but from [[precipitation hardening|precipitation]] of [[intermetallic]] compounds. The principal alloying element is 15 to 25 [[Mass fraction (chemistry)#Mass percentage|wt%]] [[nickel]].<ref name=degarmo>{{citation|last1=Degarmo|first1=E. Paul|last2=Black|first2 =J. T.|last3=Kohser|first3=Ronald A.|title=Materials and Processes in Manufacturing|publisher=Wiley|page=119|year=2003|edition=9th|isbn=0-471-65653-4}}</ref> Secondary alloying elements, which include [[cobalt]], [[molybdenum]] and [[titanium]], are added to produce intermetallic [[precipitates]].<ref name=degarmo/>

Original development (by Clarence Gieger Bieber of [[Vale Canada|Inco]] in the late 1950s) was carried out on 20 and 25 wt% Ni steels to which small additions of [[aluminium]], titanium, and [[niobium]] were made;.<ref>{{US patent|3093518}}</ref> aA rise in the price of cobalt in the late 1970s led to the development of cobalt-free maraging steels.<ref name="sha-guo">{{cite book | title=Maraging Steels: Modelling of Microstructure, Properties and Applications | first1=W | first2=Z | last1=Sha | last2=Guo | publisher=Elsevier | date=2009-10-26}}</ref>
 
The common, non-stainless grades contain 17–19 wt% nickel, 8–12 wt% cobalt, 3–5 wt% molybdenum and 0.2–1.6 wt% titanium.<ref>{{cite web |last1=INCO |title=18% Nickel Maraging Steel – Engineering Properties |url=https://nickelinstitute.org/en/library/technical-guides/18-nickel-maraging-steel-engineering-properties-4419/ |website=Nickel Institute}}</ref> Addition of chromium produces stainless grades resistant to corrosion. This also indirectly increases [[hardenability]] as they require less nickel; high-chromium, high-nickel steels are generally [[austenite|austenitic]] and unable to transform to [[martensite]] when heat treated, while lower-nickel steels can transform to martensite. Alternative variants of nickel-reduced maraging steels are based on alloys of iron and manganese plus minor additions of aluminium, nickel and titanium where compositions between Fe-9wt% Mn to Fe-15wt% Mn have been used.<ref name=maraging2>{{citation|last1= Raabe|first1=D.|last2= Sandlöbes|first2 =S.|last3= Millan|first3=J. J.|last4=Ponge|first4=D.|last5=Assadi|first5=H.|last6=Herbig|first6=M.|last7=Choi|first7=P.P.| title= Segregation engineering enables nanoscale martensite to austenite phase transformation at grain boundaries: A pathway to ductile martensite
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In the sport of [[fencing]], blades used in competitions run under the auspices of the [[Fédération Internationale d'Escrime]] are usually made with maraging steel. Maraging blades are superior for [[foil (sword)|foil]] and [[épée]] because crack propagation in maraging steel is 10 times slower than in carbon steel, resulting in less frequent breaking of the blade and fewer injuries.{{efn-lr|However, the notion that maraging steel blades break flat is a fencing [[urban legend]]. Testing has shown that the blade-breakage patterns in carbon steel and maraging steel are identical due to the similarity in the loading mode during bending. Additionally, a crack is likely to start at the same point and propagate along the same path (although much more slowly), as crack propagation in [[fatigue (material)|fatigue]] is a plastic phenomenon rather than microstructural.}}<ref name="Juvinall">{{cite book|title = Fundamentals of Machine Component Design |edition = Fourth |last1 = Juvinall |first1 = Robert C. |last2= Marshek |first2= Kurt M. |year = 2006 |publisher = John Wiley & Sons, Inc. |isbn = 978-0-471-66177-1 |page = 69}}</ref> Stainless maraging steel is used in [[bicycle]] frames (e.g. Reynolds 953 introduced in 2013)<ref>{{Cite web|title=Reynolds turns 120: The history of Reynolds Technology|url=https://www.reynoldstechnology.biz/the-history-of-reynolds-technology/|access-date=2022-12-29|website=www.reynoldstechnology.biz|date=20 December 2018 |language=en}}</ref> and [[golf]] club heads.<ref>{{Cite web|title=Maraging Steel in Golf Clubs|url=https://www.golfcompendium.com/2021/01/maraging-steel-golf-clubs.html|access-date=2022-12-29|website=Golf Compendium|language=en}}</ref> It is also used in surgical components and hypodermic syringes, but is not suitable for scalpel blades because the lack of carbon prevents it from holding a good cutting edge.
 
Maraging steel is used in oil and gas sector as downhole tools and components due to its high mechanical strength.<ref>{{cite web |url=https://powder.samaterials.com/the-impact-of-18nI300-am-maraging-steel-in-3d-printing.html |title=The Impact of 18NI300-AM Maraging Steel in 3D Printing |website=Stanford Advanced Materials |access-date=Aug 1, 2024}}</ref> The steel's resistance to [[hydrogen embrittlement]] is critical in downhole environments where exposure to [[hydrogen sulfide | hydrogen sulfide (H₂S)]] can lead to material degradation and failure.<ref>{{cite book |last1=Garrison |first1=W.M. |last2=Moody |first2=N.R |year=2012 |title=Gaseous Hydrogen Embrittlement of Materials in Energy Technologies |publisher=Woodhead Publishing |editor-last=Gangloff |editor-first=Richard |chapter=Chapter 12 - Hydrogen embrittlement of high strength steels |pages=421–492 |isbn=9781845696771}}</ref>
 
American musical instrument string producer [[Ernie Ball Inc.|Ernie Ball]] has made a specialist type of [[electric guitar]] [[Guitar string|string]] out of maraging steel, claiming that this alloy provides more output and enhanced tonal response.<ref>{{Cite web