002891201 001__ 2891201
002891201 003__ SzGeCERN
002891201 005__ 20240925092854.0
002891201 0247_ $$2DOI$$a10.1021/acsenergylett.3c01396
002891201 0248_ $$aoai:cds.cern.ch:2891201$$pcerncds:FULLTEXT$$pcerncds:CERN:FULLTEXT$$pcerncds:CERN
002891201 035__ $$9https://inspirehep.net/api/oai2d$$aoai:inspirehep.net:2765968$$d2024-03-08T14:34:56Z$$h2024-03-09T05:00:09Z$$mmarcxml
002891201 035__ $$9Inspire$$a2765968
002891201 041__ $$aeng
002891201 100__ $$aErroi, Andrea$$uMilan Bicocca U.
002891201 245__ $$9submitter$$aUltrafast and Radiation-Hard Lead Halide Perovskite Nanocomposite Scintillators
002891201 260__ $$c2023
002891201 300__ $$a12 p
002891201 520__ $$9submitter$$aThe use of scintillators for the detection of ionizing radiation is a critical aspect in many fields, including medicine, nuclear monitoring, and homeland security. Recently, lead halide perovskite nanocrystals (LHP-NCs) have emerged as promising scintillator materials. However, the difficulty of affordably upscaling synthesis to the multigram level and embedding NCs in optical-grade nanocomposites without compromising their optical properties still limits their widespread use. In addition, fundamental aspects of the scintillation mechanisms are not fully understood, leaving the scientific community without suitable fabrication protocols and rational guidelines for the full exploitation of their potential. In this work, we realize large polyacrylate nanocomposite scintillators based on CsPbBr3 NCs, which are synthesized via a novel room temperature, low waste turbo-emulsification approach, followed by their in situ transformation during the mass polymerization process. The interaction between NCs and polymer chains strengthens the scintillator structure, homogenizes the particle size distribution and passivates NC defects, resulting in nanocomposite prototypes with luminescence efficiency >90%, exceptional radiation hardness, 4800 ph/MeV scintillation yield even at low NC loading, and ultrafast response time, with over 30% of scintillation occurring in the first 80 ps, promising for fast-time applications in precision medicine and high-energy physics. Ultrafast radioluminescence and optical spectroscopy experiments using pulsed synchrotron light further disambiguate the origin of the scintillation kinetics as the result of charged-exciton and multiexciton recombination formed under ionizing excitation. This highlights the role of nonradiative Auger decay, whose potential impact on fast timing applications we anticipate via a kinetic model.
002891201 540__ $$3publication$$aCC-BY-4.0$$fOther$$uhttps://creativecommons.org/licenses/by/4.0/
002891201 542__ $$3publication$$dThe Authors$$g2023
002891201 65017 $$2INSPIRE$$aOther
002891201 690C_ $$aARTICLE
002891201 690C_ $$aCERN
002891201 700__ $$aMecca, Sara$$uMilan Bicocca U.
002891201 700__ $$aZaffalon, Matteo L$$uMilan Bicocca U.
002891201 700__ $$aFrank, Isabel$$uCERN$$uMunich U.$$vLMU Munich, Geschwister-Scholl-Platz 1, 80539 Munich, Germany
002891201 700__ $$aCarulli, Francesco$$uMilan Bicocca U.
002891201 700__ $$aCemmi, Alessia$$uENEA, Rome
002891201 700__ $$aDi Sarcina, Ilaria$$uENEA, Rome
002891201 700__ $$aDebellis, Doriana$$uItalian Inst. Tech., Genoa
002891201 700__ $$aRossi, Francesca$$uParma, IMSEM
002891201 700__ $$aCova, Francesca$$uMilan Bicocca U.
002891201 700__ $$aPauwels, Kristof$$uESRF, Grenoble
002891201 700__ $$aMauri, Michele$$uMilan Bicocca U.
002891201 700__ $$aPerego, Jacopo$$uMilan Bicocca U.
002891201 700__ $$aPinchetti, Valerio$$uMilan Bicocca U.
002891201 700__ $$aComotti, Angiolina$$uMilan Bicocca U.
002891201 700__ $$aMeinardi, Francesco$$uMilan Bicocca U.
002891201 700__ $$aVedda, Anna$$uMilan Bicocca U.
002891201 700__ $$aAuffray, Etiennette$$uCERN
002891201 700__ $$aBeverina, Luca$$uMilan Bicocca U.
002891201 700__ $$aBrovelli, Sergio$$uMilan Bicocca U.
002891201 773__ $$c3883-3894$$n9$$pACS Energy Letters$$v8$$y2023
002891201 8564_ $$82517020$$s5507722$$uhttps://cds.cern.ch/record/2891201/files/erroi-et-al-2023-ultrafast-and-radiation-hard-lead-halide-perovskite-nanocomposite-scintillators.pdf$$yFulltext
002891201 960__ $$a13
002891201 980__ $$aARTICLE